1,4-Benzenediamine, N,N,N',N'-tetrakis(3-methylphenyl)- | 129764-80-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,4-Benzenediamine, N,N,N',N'-tetrakis(3-methylphenyl)-
• 英文别名: 1-N,1-N,4-N,4-N-tetrakis(3-methylphenyl)benzene-1,4-diamine
• CAS: 129764-80-3
• 化学式: C₃₄H₃₂N₂
• 分子量: 468.6
• InChiKey: MBRXYYRVMRQLKQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.9
• 重原子数：
  36
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Transition metal complexes comprising carbene ligands serving as emitters for organic light-emitting diodes (OLED's)
  申请人：UDC Ireland Limited

  公开号：US10573828B2

  公开（公告）日：2020-02-25

  Use of transition metal complexes of the formula (I) in organic light-emitting diodes where: M1 is a metal atom; carbene is a carbene ligand; L is a monoanionic or dianionic ligand; K is an uncharged monodentate or bidentate ligand selected from the group consisting of phosphines; CO; pyridines; nitriles and conjugated dienes which form a π complex with M1; n is the number of carbene ligands and is at least 1; m is the number of ligands L, where m can be 0 or ≥1; o is the number of ligands K, where o can be 0 or ≥1; where the sum n+m+o is dependent on the oxidation state and coordination number of the metal atom and on the denticity of the ligands carbene, L and K and also on the charge on the ligands carbene and L, with the proviso that n is at least 1, and also an OLED comprising these transition metal complexes, a light-emitting layer comprising these transition metal complexes, OLEDs comprising this light-emitting layer, devices comprising an OLED according to the present invention, and specific transition metal complexes comprising at least two carbene ligands.

  公式（I）中的过渡金属配合物在有机发光二极管中的应用，其中：M1是金属原子；carbene是卡宾配体；L是单阴离子或双阴离子配体；K是未带电的单或双齿配体，选自膦；CO；吡啶；腈和共轭二烯，与M1形成π配合物；n是卡宾配体的数量，至少为1；m是配体L的数量，其中m可以是0或≥1；o是配体K的数量，其中o可以是0或≥1；其中n+m+o的总和取决于金属原子的氧化态和配位数，以及配体carbene、L和K的配位性，还取决于配体carbene和L的电荷，但n至少为1；此外，还包括至少具有两个卡宾配体的特定过渡金属配合物。还包括包含这些过渡金属配合物的OLED、包含这些过渡金属配合物的发光层、包含这种发光层的OLED、包括根据本发明的OLED的装置。
• Composite material, light emitting element, light emitting device and electronic appliance using the composite material
  申请人：Semiconductor Energy Laboratory Co, Ltd.

  公开号：EP2423994A1

  公开（公告）日：2012-02-29

  A composite material includes an organic compound represented by the following general formula (2) and an inorganic compound, where, in the general formula (2), where in the general formula (2) X is selected from aromatic hydrocarbons represented by formulae (2-1) to (2-6) and R1 to R20 are identical or different from one another, and represent any of hydrogen, an alkyl group, an alkoxy group, an aryl group, and an arylalkyl group. A light emitting element includes the composite material and a light emitting device and an electronic appliance includes the light emitting element. The composite material has an excellent carrier transporting property and an excellent carrier injecting property with respect to the organic compound along with high visible light transmittance. By utilizing the composite material, a current excitation type light emitting element requiring low driving voltage and having excellent light emitting efficiency is obtained. By using the light emitting element, a light emitting device consuming low power and an electronic appliance including the light emitting device is provided.

  一种复合材料包括由以下通式（2）表示的有机化合物和无机化合物，其中，在通式（2）中，通式（2）中的X选自由式（2-1）至（2-6）表示的芳香烃，R1至R20彼此相同或不同，并代表氢、烷基、烷氧基、芳基和芳烷基中的任何一种。发光元件包括该复合材料，发光器件和电子设备包括该发光元件。相对于有机化合物而言，复合材料具有优异的载流子传输性能和优异的载流子注入性能，同时还具有较高的可见光透射率。利用这种复合材料，可以获得一种需要低驱动电压且发光效率极高的电流激发型发光元件。通过使用该发光元件，还可提供低功耗的发光器件和包括该发光器件的电子设备。
• Transition metal complexes comprising carbene ligands serving as emitters for organic light-emitting diodes (oled's)
  申请人：Bold Markus

  公开号：US20060258043A1

  公开（公告）日：2006-11-16

  Use of transition metal complexes of the formula (I) in organic light-emitting diodes where: M 1 is a metal atom; carbene is a carbene ligand; L is a monoanionic or dianionic ligand; K is an uncharged monodentate or bidentate ligand selected from the group consisting of phosphines; CO; pyridines; nitrites and conjugated dienes which form a π complex with M 1 ; n is the number of carbene ligands and is at least 1; m is the number of ligands L, where m can be 0 or ≧1; o is the number of ligands K, where o can be 0 or ≧1; where the sum n+m+o is dependent on the oxidation state and coordination number of the metal atom and on the denticity of the ligands carbene, L and K and also on the charge on the ligands carbene and L, with the proviso that n is at least 1, and also an OLED comprising these transition metal complexes, a light-emitting layer comprising these transition metal complexes, OLEDs comprising this light-emitting layer, devices comprising an OLED according to the present invention, and specific transition metal complexes comprising at least two carbene ligands.
• Method for producing tris-ortho-metallated complexes and use of such complexes in oleds
  申请人：Bold Markus

  公开号：US20070080342A1

  公开（公告）日：2007-04-12

  Process for preparing tris-ortho-metallated iridium complexes of the formula (I) where R 1 , R 2 , R 3 , R 4 , R 5 , R 6 and X have the meanings given in the description, Ir complexes which can be prepared by the process of the invention, the use of the Ir complexes as emitter molecule in organic light-emitting diodes (OLEDs), a light-emitting layer comprising the Ir complexes, an OLED comprising this light-emitting layer and an apparatus comprising an OLED according to the present invention.
• Synthesis of Polynaphthalenes and Their Use
  申请人：Doetz Florian

  公开号：US20070287821A1

  公开（公告）日：2007-12-13

  The present invention relates to a process for preparing polynaphthalene derivatives comprising repeating units of the general formula Ia and/or Ib where R 1 , R 2 , R 1′ , R 2′ are as defined in the description. The present invention further relates to polynaphthalene derivatives which can be prepared by the process of the invention, films comprising or consisting of at least one polynaphthalene derivative according to the invention, organic light-emitting diodes (OLEDs) comprising at least one polynaphthalene derivative according to the invention, a light-emitting layer comprising or consisting of at least one polynaphthalene derivative according to the invention, an OLED comprising the light-emitting layer of the invention, devices comprising an OLED according to the invention and the use of the polynaphthalene derivatives of the invention as emitter substances in OLEDs.