2-hydroxy-3-phenylaminocarbonyl-6-hydroxycarbonylnaphthalene | 183962-84-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-hydroxy-3-phenylaminocarbonyl-6-hydroxycarbonylnaphthalene
• 英文别名: 6-hydroxy-7-(phenylcarbamoyl)naphthalene-2-carboxylic acid
• CAS: 183962-84-7
• 化学式: C₁₈H₁₃NO₄
• 分子量: 307.306
• InChiKey: NSDVECJQIFQXCR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  86.6
• 氢给体数：
  3
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  sodium 3-phenylaminocarbonyl-6-methoxycarbonyl-2-naphthoate 、 水 、 sodium hydroxide 在 ice 、 水 作用下， 以 甲醇 为溶剂， 反应 16.0h， 以to obtain 0.057 g of 2-hydroxy-3-phenylaminocarbonyl-6-hydroxycarbonylnaphthalene的产率得到2-hydroxy-3-phenylaminocarbonyl-6-hydroxycarbonylnaphthalene
  参考文献：
  名称：

  Naphthol derivatives and process for producing the same

  摘要：

  一种萘酚衍生物，由通式（I）表示，其中Y和Y'表示--（CONH）.sub.n --X或--COR; X是苯基，萘基，蒽醌基，苯并咪唑基或咔唑基; R是羟基，具有1至6个碳原子的烷氧基，卤素原子，苄氧基，苯氧基或苯乙酰氧基; R.sub.2是氢原子，碱金属，具有1至6个碳原子的烷基，具有1至6个碳原子的酰基或苯基烷基; Z是从氢原子，卤素原子，硝基，亚硝基和氨基（Z可以取代萘环的任何环）的群中选择的群; n是1或2的整数; 前提是当R同时表示羟基时，R.sub.2和Z不同时表示氢原子！以及一种制备该萘酚衍生物的方法。该萘酚衍生物可用作合成染料，颜料，感光材料等的原材料。

  公开号：

  US05786523A1

文献信息

• Naphthol derivatives and process for producing the same
  申请人：Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo

  公开号：US06252104B1

  公开（公告）日：2001-06-26

  A naphthol derivative represented by the general formula (I), [wherein Y and Y′ indicate —(CONH)n—X or —COR; X is a phenyl group, a naphthyl group, an anthraquinonyl group, a benzimidazolonyl group or a carbazolyl group; R is a hydroxyl group, an alkoxy group having 1 to 6 carbon atoms, a halogen atom, a benzyloxy group, a phenyloxy group or a phenacyloxy group; R2 is a hydrogen atom, an alkaline metal, an alkyl group having 1 to 6 carbon atoms, an acyl group having 1 to 6 carbon atoms or a phenylalkyl group; Z is a group selected from the group consisting of a hydrogen atom, a halogen atom, a nitro group, a nitroso group and an amino group (Z may be substituted on any ring of the naphthalene ring); and n is an integer of 1 or 2; provided that R2 and Z do not simultaneously indicate a hydrogen atom when both R simultaneously indicate a hydroxyl group], and a process for producing the same. This naphthol derivative can be used as raw materials for synthesis, such as dyes, pigments, photosensitive materials and the like.

  一种萘酚衍生物，由通式（I）表示，其中Y和Y'表示—（CONH）n—X或—COR；X是苯基、萘基、蒽醌基、苯并咪唑基或咔唑基；R是羟基、具有1至6个碳原子的烷氧基、卤素原子、苄氧基、苯氧基或苯乙酰氧基；R2是氢原子、碱金属、具有1至6个碳原子的烷基、具有1至6个碳原子的酰基或苯基烷基；Z是选自氢原子、卤素原子、硝基、亚硝基和氨基的基团（Z可以取代萘环的任何一个环上）；n是1或2的整数；前提是当R同时表示羟基时，R2和Z不同时表示氢原子。本萘酚衍生物可用作合成染料、颜料、感光材料等原材料的原料。
• Method for producing naphthalene carboxylic acid amide compound
  申请人：Wakamori Hiroyuki

  公开号：US20080045720A1

  公开（公告）日：2008-02-21

  The present invention provides a method for producing a naphthalenecarboxylic acid amide compound represented by formula [1] comprising, reacting a naphthalenecarboxylic acid halide compound represented by formula [2] with ammonium acetate in a solvent having an ether bond. According to the method of the present invention, a naphthalene carboxylic acid amide compound can be obtained at high yield and at low cost.

  本发明提供了一种制备萘甲酸酰胺化合物（由式[1]表示）的方法，包括将由式[2]表示的萘甲酸卤化物与醋酸铵在具有醚键的溶剂中反应。根据本发明的方法，可以以高收率和低成本获得萘甲酸酰胺化合物。
• NAPHTHOL DERIVATIVES AND PROCESS FOR PRODUCING THE SAME
  申请人：KABUSHIKIKAISHA UENO SEIYAKU OYO KENKYUJO

  公开号：EP0765858A1

  公开（公告）日：1997-04-02

  A naphthol derivative represented by the general formula (I) [wherein Y and Y' indicate -(CONH)n-X or -COR; X is a phenyl group, a naphthyl group, an anthraquinonyl group, a benzimidazolonyl group or a carbazolyl group; R is a hydroxyl group, an alkoxy group having 1 to 6 carbon atoms, a halogen atom, a benzyloxy group, a phenyloxy group or a phenacyloxy group; R2 is a hydrogen atom, an alkaline metal, an alkyl group having 1 to 6 carbon atoms, an acyl group having 1 to 6 carbon atoms or a phenylalkyl group; Z is a group selected from the group consisting of a hydrogen atom, a halogen atom, a nitro group, a nitroso group and an amino group (Z may be substituted on any ring of the naphthalene ring); and n is an integer of 1 or 2; provided that R2 and Z do not simultaneously indicate a hydrogen atom when both R simultaneously indicate a hydroxyl group], and a process for producing the same. This naphthol derivative can be used as raw materials for synthesis, such as dyes, pigments, photosensitive materials and the like.

  通式(I)代表的萘酚衍生物[其中Y和Y'表示-(CONH)n-X或-COR；X是苯基、萘基、蒽醌基、苯并咪唑基或咔唑基；R 是羟基、1 至 6 个碳原子的烷氧基、卤素原子、苄氧基、苯氧基或苯乙氧基； R2 是氢原子、碱金属、1 至 6 个碳原子的烷基、1 至 6 个碳原子的酰基或苯基烷基；Z 是选自氢原子、卤素原子、硝基、亚硝基和氨基（Z 可在萘环的任何环上被取代）的基团；以及 n 是 1 或 2 的整数；条件是当两个 R 同时表示羟基时，R2 和 Z 不同时表示氢原子]，以及生产该衍生物的工艺。这种萘酚衍生物可用作染料、颜料、感光材料等合成原料。
• BIS(AMINOCARBONYLNAPHTHOL) DERIVATIVE
  申请人：KABUSHIKIKAISHA UENO SEIYAKU OYO KENKYUJO

  公开号：EP0882705A1

  公开（公告）日：1998-12-09

  The present invention provides a bis (aminocarbonylnaphthol) derivative which is useful as a raw material for novel azo pigments by bisamidation of each one carboxyl group of two 2-hydroxynaphthalene-3, 6-dicarboxylic acids using an aliphatic or aromatic diamine.

  本发明提供了一种双（氨基羰基萘酚）衍生物，该衍生物可用作新型偶氮颜料的原料，其方法是使用脂肪族或芳香族二胺将两个 2-羟基萘-3，6-二羧酸的每一个羧基进行双酰胺化。
• WATER-SOLUBLE AZO COMPOUNDS AND PROCESS FOR PRODUCING THE SAME
  申请人：Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo

  公开号：EP0937753A1

  公开（公告）日：1999-08-25

  The present invention provides novel water-soluble azo compounds derived from 2-hydroxynaphthalene-3,6-dicarboxylic acid or derivatives thereof and diazonium salts having sulfo group(s). These compounds are useful as raw materials for dyes having excellent dyeing properties and fastness.

  本发明提供了由 2-羟基萘-3,6-二羧酸或其衍生物和具有磺基的重氮盐衍生的新型水溶性偶氮化合物。这些化合物可用作具有优异染色性能和牢度的染料原料。