1-(3-dichlorophosphoryloxyphenyl)-N-[5-[(3-dichlorophosphoryloxyphenyl)methylideneamino]naphthalen-1-yl]methanimine | 1426080-55-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-(3-dichlorophosphoryloxyphenyl)-N-[5-[(3-dichlorophosphoryloxyphenyl)methylideneamino]naphthalen-1-yl]methanimine
• CAS: 1426080-55-8
• 化学式: C₂₄H₁₆Cl₄N₂O₄P₂
• 分子量: 600.162
• InChiKey: SGBCJMSPEVCLII-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  36
• 可旋转键数：
  8
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  77.3
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1-(3-dichlorophosphoryloxyphenyl)-N-[5-[(3-dichlorophosphoryloxyphenyl)methylideneamino]naphthalen-1-yl]methanimine 、 间羟基苯甲醛 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 5.33h， 以75%的产率得到[3-[[5-[[3-Bis(3-formylphenoxy)phosphoryloxyphenyl]methylideneamino]naphthalen-1-yl]iminomethyl]phenyl] bis(3-formylphenyl) phosphate
  参考文献：
  名称：

  Synthesis, Characterization, and Thermogravimetric Studies of a Phosphorus-Containing Dendron Built from 1,5-Diaminonaphthalene at the Core

  摘要：

  A facile divergent synthesis of a phosphorus-containing dendron containing 1,5-diaminonaphthalene is described. The phosphorus-containing dendron, functionalized with a 1,5-diaminonaphthalene unit at the core and phenolic OH groups grafted at the periphery, has been accomplished in a versatile, simple fashion, using Schiff's condensation and nucleophilic substitution reactions with POCl3, 3-hydroxy-benzaldehyde, 4-hydroxy-benzaldehyde, and 3-amino-phenol iteratively. The structures of intermediate dendrons were characterized by infrared, NMR (H-1, C-13, and P-31), liquid chromatography-mass spectrometry, and C, H, N analysis. The structure of the final dendron (6) was confirmed by infrared, NMR (H-1, C-13, and P-31), matrix-assisted laser desorption/ionization time-of-flight mass spectrometry, and C, H, N analysis. The thermal stability and degradation of the resulting final dendron was checked by thermal gravitometric analysis/differential thermal analysis.

  DOI：

  10.1080/00397911.2011.628773
• 作为产物：
  描述：

  1,5-萘二胺 在 三乙胺 、 三氯氧磷 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 反应 9.33h， 生成 1-(3-dichlorophosphoryloxyphenyl)-N-[5-[(3-dichlorophosphoryloxyphenyl)methylideneamino]naphthalen-1-yl]methanimine
  参考文献：
  名称：

  Synthesis, Characterization, and Thermogravimetric Studies of a Phosphorus-Containing Dendron Built from 1,5-Diaminonaphthalene at the Core

  摘要：

  A facile divergent synthesis of a phosphorus-containing dendron containing 1,5-diaminonaphthalene is described. The phosphorus-containing dendron, functionalized with a 1,5-diaminonaphthalene unit at the core and phenolic OH groups grafted at the periphery, has been accomplished in a versatile, simple fashion, using Schiff's condensation and nucleophilic substitution reactions with POCl3, 3-hydroxy-benzaldehyde, 4-hydroxy-benzaldehyde, and 3-amino-phenol iteratively. The structures of intermediate dendrons were characterized by infrared, NMR (H-1, C-13, and P-31), liquid chromatography-mass spectrometry, and C, H, N analysis. The structure of the final dendron (6) was confirmed by infrared, NMR (H-1, C-13, and P-31), matrix-assisted laser desorption/ionization time-of-flight mass spectrometry, and C, H, N analysis. The thermal stability and degradation of the resulting final dendron was checked by thermal gravitometric analysis/differential thermal analysis.

  DOI：

  10.1080/00397911.2011.628773

文献信息

• Synthesis, Characterization, and Thermogravimetric Studies of a Phosphorus-Containing Dendron Built from 1,5-Diaminonaphthalene at the Core
  作者：E. Dadapeer、B. Satheesh Krishna、C. Naga Raju

  DOI：10.1080/00397911.2011.628773

  日期：2013.5.3

  A facile divergent synthesis of a phosphorus-containing dendron containing 1,5-diaminonaphthalene is described. The phosphorus-containing dendron, functionalized with a 1,5-diaminonaphthalene unit at the core and phenolic OH groups grafted at the periphery, has been accomplished in a versatile, simple fashion, using Schiff's condensation and nucleophilic substitution reactions with POCl3, 3-hydroxy-benzaldehyde, 4-hydroxy-benzaldehyde, and 3-amino-phenol iteratively. The structures of intermediate dendrons were characterized by infrared, NMR (H-1, C-13, and P-31), liquid chromatography-mass spectrometry, and C, H, N analysis. The structure of the final dendron (6) was confirmed by infrared, NMR (H-1, C-13, and P-31), matrix-assisted laser desorption/ionization time-of-flight mass spectrometry, and C, H, N analysis. The thermal stability and degradation of the resulting final dendron was checked by thermal gravitometric analysis/differential thermal analysis.