2-Decyl-1-ethynylnaphthalene | 923972-66-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-Decyl-1-ethynylnaphthalene
• 英文别名: 2-decyl-1-ethynylnaphthalene
• CAS: 923972-66-1
• 化学式: C₂₂H₂₈
• 分子量: 292.5
• InChiKey: UJKAYXHGZWRGDW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  22
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  (l)-1-ethynyl-2-n-hexylnaphthalene 、 溴己烷 、 癸基溴 生成 2-Decyl-1-ethynylnaphthalene
  参考文献：
  名称：

  Acetylene-Based Polymer

  摘要：

  一种基于乙炔的聚合物，包括由以下式子(1)表示的n个重复单元：CH═CAn(1)其中，n为10到10,000的整数；每个A代表从萘基，菲基，芘基和蒽基中选择的一种基团，该基团是单取代或双取代的，所选的基团包括烷基，芳香碳氢基取代的烷基，R1-O-基团，-S-R2基团，-NR3R4基团，氰基，羧基，R5SO2-基团，-COOR6基团，-CON(R7)(R8)基团和-COR9基团（其中R1、R5、R6和R9均为烷基，R2、R3、R4、R7和R8均为氢原子或烷基）；并且这些重复单元可以相同或不同。

  公开号：

  US20090253872A1

文献信息

• Acetylene-Based Polymer
  申请人：Tsuchihara Kenji

  公开号：US20090253872A1

  公开（公告）日：2009-10-08

  An acetylene-based polymer, comprising n recurring units represented by the following Formula ( 1 ): CH═CA n (1) wherein, n is an integer of 10 to 10,000; each A represents a group selected from a naphthyl group, a phenanthryl group, a pyrenyl group and an anthryl group, which is mono- or di-substituted with a group selected from alkyl groups, alkyl groups substituted with aromatic hydrocarbon groups, R 1 —O— groups, —S—R 2 groups, —NR 3 R 4 groups, a cyano group, a carboxyl group, R 5 SO 2 — groups, —COOR 6 groups, —CON(R 7 )(R 8 ) groups and —COR 9 groups (each of R 1 , R 5 , R 6 and R 9 is an alkyl group, each of R 2 , R 3 , R 4 , R 7 and R 8 is a hydrogen atom or an alkyl group); and the recurring units may be the same as or different from each other.

  一种基于乙炔的聚合物，包括由以下式子(1)表示的n个重复单元：CH═CAn(1)其中，n为10到10,000的整数；每个A代表从萘基，菲基，芘基和蒽基中选择的一种基团，该基团是单取代或双取代的，所选的基团包括烷基，芳香碳氢基取代的烷基，R1-O-基团，-S-R2基团，-NR3R4基团，氰基，羧基，R5SO2-基团，-COOR6基团，-CON(R7)(R8)基团和-COR9基团（其中R1、R5、R6和R9均为烷基，R2、R3、R4、R7和R8均为氢原子或烷基）；并且这些重复单元可以相同或不同。
• Light Control Material and Light Control Film
  申请人：Yahara Kazuyuki

  公开号：US20090080056A1

  公开（公告）日：2009-03-26

  The present invention aims to provide a light control material capable of optionally controlling the light transmittance in an arbitrary wavelength range among a wide wavelength range, and a light control film formed by using the light control material. The present invention provides a light control material, which comprises a stimulus sensitive resin and is capable of controlling the light transmittance in a specific wavelength range, the stimulus sensitive resin being a polyacetylene compound having a repeating unit represented by the following general formula (1): CH═CR 1  n [Chemical Formula 1] ( 1 ) in the formula (1), R 1 represents a naphthalene group, a phenanthrene group, a pyrenyl group or an anthracene group, each of the four groups being substituted by a group selected from the group consisting of: an alkyl group having 1 to 40 carbon atoms, an alkoxy group (with an alkyl group having 1 to 40 carbon atoms), an SR 4 group (R 4 represents a hydrogen atom or an alkyl group having 1 to 40 carbon atoms), an NR 5 R 6 group (R 5 and R 6 may be the same or different, and each represents a hydrogen atom or a group selected from alkyl groups having 1 to 40 carbon atoms), a cyano group, a carboxy group, a sulfoxyl group, an ester group, an amide group and COR 7 (R 7 represents an alkyl group having 1 to 40 carbon atoms), or the following general formula (2): CR 2 ═CR 3  n [Chemical Formula 2] ( 2 ) in the formula (2), R 2 represents a naphthalene group or an anthracene group; R 3 represents a phenyl group substituted by a substituent X at the position m or the position p; and the substituent X represents a group selected from the group consisting of: an alkyl group having 1 to 20 carbon atoms, an alkoxy group (with an alkyl group having 1 to 20 carbon atoms), an SR 4 group (R 4 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms), an NR 5 R 6 group (R 5 and R 6 may be the same or different, and each represents a hydrogen atom or a group selected from alkyl groups having 1 to 20 carbon atoms), a cyano group, a carboxy group, a sulfoxyl group, an ester group, an amide group and COR 7 (R 7 represents an alkyl group having 1 to 20 carbon atoms).

  本发明旨在提供一种光控制材料，能够在宽波长范围内任意控制特定波长范围内的光透过率，并使用该光控制材料制成的光控制膜。本发明提供了一种光控制材料，包括一种刺激敏感树脂，能够控制特定波长范围内的光透过率，其中刺激敏感树脂是一种聚乙烯化合物，具有由下列通式（1）表示的重复单元：CH═CR1n[化学式1]（1）在式（1）中，R1表示萘基，菲基，芘基或蒽基，四个基中的每一个都被选自由由以下基团组成的基团所取代：1至40个碳原子的烷基，（带有1至40个碳原子的烷基）的烷氧基，SR4基团（R4表示氢原子或1至40个碳原子的烷基），NR5R6基团（R5和R6可以相同也可以不同，每个表示氢原子或选自由1至40个碳原子的烷基组成的基团），氰基，羧基，亚磺酰基，酯基，酰胺基和COR7（R7表示1至40个碳原子的烷基）；或下列通式（2）：CR2═CR3n[化学式2]（2）在式（2）中，R2表示萘基或蒽基；R3表示在位置m或位置p处被取代基团X取代的苯基；取代基团X表示选自由以下基团组成的基团：1至20个碳原子的烷基，（带有1至20个碳原子的烷基）的烷氧基，SR4基团（R4表示氢原子或1至20个碳原子的烷基），NR5R6基团（R5和R6可以相同也可以不同，每个表示氢原子或选自由1至20个碳原子的烷基组成的基团），氰基，羧基，亚磺酰基，酯基，酰胺基和COR7（R7表示1至20个碳原子的烷基）。
• Light control material and light control film
  申请人：Sekisui Chemical Co., Ltd.

  公开号：US07715083B2

  公开（公告）日：2010-05-11

  The present invention aims to provide a light control material capable of optionally controlling the light transmittance in an arbitrary wavelength range among a wide wavelength range, and a light control film formed by using the light control material.

  本发明旨在提供一种光控制材料，能够在广泛的波长范围内任意控制波长范围内的光透过率，并且使用该光控制材料形成的光控制膜。
• Acetylene-based polymer
  申请人：National Institute of Advanced Industrial Science and Technology

  公开号：US07977441B2

  公开（公告）日：2011-07-12

  An acetylene-based polymer, comprising n recurring units represented by the following Formula (1): CH═CAn  (1) wherein, n is an integer of 10 to 10,000; each A represents a group selected from a naphthyl group, a phenanthryl group, a pyrenyl group and an anthryl group, which is mono- or di-substituted with a group selected from alkyl groups, alkyl groups substituted with aromatic hydrocarbon groups, R1—O— groups, —S—R2 groups, —NR3R4 groups, a cyano group, a carboxyl group, R5SO2— groups, —COOR6 groups, —CON(R7)(R8) groups and —COR9 groups (each of R1, R5, R6 and R9 is an alkyl group, each of R2, R3, R4, R7 and R8 is a hydrogen atom or an alkyl group); and the recurring units may be the same as or different from each other.

  一种基于乙炔的聚合物，包括由以下公式（1）表示的n个重复单元：CH═CAn  (1)，其中n为10到10,000之间的整数；每个A代表从萘基，菲基，芘基和蒽基中选择的一个基团，该基团是单取代或双取代的，所选择的基团来自烷基，芳香碳氢基取代的烷基，R1-O-基团，-S-R2基团，-NR3R4基团，氰基，羧基，R5SO2-基团，-COOR6基团，-CON（R7）（R8）基团和-COR9基团（其中R1、R5、R6和R9均为烷基，R2、R3、R4、R7和R8为氢原子或烷基）；重复单元可以相同或不同。