4-butoxy-N-(4-butoxyphenyl)-N-(4-ethynylphenyl)benzenamine | 521941-20-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-butoxy-N-(4-butoxyphenyl)-N-(4-ethynylphenyl)benzenamine
• 英文别名: 4-Butoxy-N-(4-butoxyphenyl)-N-(4-ethynylphenyl)aniline；N,N-bis(4-butoxyphenyl)-4-ethynylaniline
• CAS: 521941-20-8
• 化学式: C₂₈H₃₁NO₂
• 分子量: 413.56
• InChiKey: VLDVPMFAGCEIBY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  31
• 可旋转键数：
  12
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  21.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-butoxy-N-(4-butoxyphenyl)-N-(4-ethynylphenyl)benzenamine 、 在 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 、 三乙胺 、 三苯基膦 作用下， 以 甲苯 为溶剂， 反应 5.0h， 以51.71%的产率得到4-(5-(4-(5-((4-(bis(4-butoxyphenyl)amino)phenyl)ethynyl)thiophen-2-yl)-2,5-bis(2-ethylhexyl)-3,6-dioxo-2,3,5,6-tetrahydropyrrolo[3,4-c]pyrrol-1-yl)thiophen-2-yl)benzaldehyde
  参考文献：
  名称：

  Blue-colored dyes featuring a diketopyrrolopyrrole spacer for translucent dye-sensitized solar cells

  摘要：

  We report the facile synthesis of blue-colored dyes featuring a diketopyrrolopyrrole (DPP) spacer with dimethylamine and bis(4-dibuotxylphenyl)-phenyl-amine as donor residues (CSD-08 and CSD-09), their spectroscopic, electrochemical and colorific properties, and their application to translucent dye-sensitized solar cells (DSSCs). In the DSSCs fabricated with 5 mu m-thick TiO2 photoanodes, CSD-08 and CSD-09 yield power-conversion-efficiencies of 3.43% and 3.62%, respectively, under simulated one sun illumination.

  DOI：

  10.1016/j.dyepig.2019.107840

文献信息

• Blue-colored dyes featuring a diketopyrrolopyrrole spacer for translucent dye-sensitized solar cells
  作者：Dong-suk Lim、Kyungah Choi、Dini Hayati、Da-Heon Park、Alvien Ghifari、Kang Min Lee、Yohan Ko、Yongseok Jun、Hyeon-Jeong Suk、Jongin Hong

  DOI：10.1016/j.dyepig.2019.107840

  日期：2020.2

  We report the facile synthesis of blue-colored dyes featuring a diketopyrrolopyrrole (DPP) spacer with dimethylamine and bis(4-dibuotxylphenyl)-phenyl-amine as donor residues (CSD-08 and CSD-09), their spectroscopic, electrochemical and colorific properties, and their application to translucent dye-sensitized solar cells (DSSCs). In the DSSCs fabricated with 5 mu m-thick TiO2 photoanodes, CSD-08 and CSD-09 yield power-conversion-efficiencies of 3.43% and 3.62%, respectively, under simulated one sun illumination.