2,2-dimethyl-11-isopropyl-11-amino-undeca-4,8-dienal-oxime | 74926-28-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2,2-dimethyl-11-isopropyl-11-amino-undeca-4,8-dienal-oxime
• 英文别名: N-(11-Amino-2,2,12-trimethyltrideca-4,8-dien-1-ylidene)hydroxylamine；N-(11-amino-2,2,12-trimethyltrideca-4,8-dienylidene)hydroxylamine
• CAS: 74926-28-6
• 化学式: C₁₆H₃₀N₂O
• 分子量: 266.427
• InChiKey: XKBQSUGDDYFSTO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  19
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  58.6
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,2-dimethyl-11-isopropyl-11-amino-undeca-4,8-dienal-oxime 、 2,2-Dimethyl-11-isopropyl-11-amino-undeca-4,8-dienal phenylhydrazine 、 、 2,2-dimethyl-11-isopropyl-11-aminoundeca-4,8-dienal-semicarbazone 在 1-isopropyl-10,10-dimethyl-1,11-diamino-undecaneis 作用下， 以2,2-dimethyl-11-isopropyl-11-amino-undecanal-benzylamine (prepared according to Example 27), 1-isopropyl-10,10-dimethyl-1,11-diamino-undecaneis obtained in a yield of 76% of theory, 60.6% of theory, 62.6% of theory and 72% of theory respectively的产率得到2,2-Dimethyl-11-isopropyl-11-amino-undecanal benzylamine
  参考文献：
  名称：

  Substituted 11-amino-undeca-4,8-dienal and 11-amino-undecanal

  摘要：

  本文描述了式Ia和Ib的衍生物的制备方法，其中化合物为11-氨基十一烯-4,8-二醛和11-氨基十一醛，其化学式为：##STR1## 在此式中，R.sub.1到R.sub.6，Y和m的定义如专利要求1所述。公式Ia和Ib的化合物可以通过催化氢化制备新型1,11-二氨基十一烷，该化合物可以用于制备聚合物，特别是透明聚酰胺，或作为环氧树脂的固化剂。

  公开号：

  US04277621A1
• 作为产物：
  描述：

  3,3-dimethyl-12-isopropyl-1-aza-1,5,9-cyclododecatriene 在 盐酸 、 盐酸羟胺 作用下， 以 水 为溶剂， 生成 2,2-dimethyl-11-isopropyl-11-amino-undeca-4,8-dienal-oxime
  参考文献：
  名称：

  Substituted 1,11-diaminoundecanes, processes for producing them, and

  摘要：

  描述了新型取代的1,11-二胺十一烷，特别是那些符合以下式的化合物[R.sub.1是具有1-12个碳原子的烷基，R.sub.2是氢或具有1-12个碳原子的烷基，R.sub.3是具有1-12个碳原子的烷基，环烷基具有4-12个碳原子，芳基具有7或8个碳原子，未取代或取代的芳基，吡啶基，呋喃基或噻吩基，R.sub.4是氢，具有1-12个碳原子的烷基，环烷基具有4-12个碳原子，或未取代或取代的芳基，或者R.sub.1和R.sub.2和/或R.sub.3和R.sub.4一起是具有3-11个碳原子的亚基]，以及生产它们的过程。式I的化合物可以用于生产聚缩酸酯产品，特别是聚酰胺。它们也可以用作环氧树脂的固化剂。

  公开号：

  US04460790A1

文献信息

• Substituted 1,11-diaminoundecanes, processes for producing them and
  申请人：Ciba-Geigy Corporation

  公开号：US04484004A1

  公开（公告）日：1984-11-20

  There are described novel substituted 1,11-diaminoundecanes, particularly those of the formula ##STR1## [R.sub.1 is alkyl having 1-12 C atoms, R.sub.2 is hydrogen or alkyl having 1-12 C atoms, R.sub.3 is alkyl having 1-12 C atoms, cycloalkyl having 4-12 C atoms, aralkyl having 7 or 8 C atoms, unsubstituted or substituted aryl, pyridyl, furyl or thienyl, R.sub.4 is hydrogen, alkyl having 1-12 C atoms, cycloalkyl having 4-12 C atoms, or unsubstituted or substituted aryl, or R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 together are alkylene having 3-11 C atoms], and processes for producing them. The compound of the formula I can be used for example for producing polycondensation products, particularly polyamides. They can be used also as curing agents for epoxide resins.

  描述了新型的取代的1,11-二氨基十一烷，特别是公式##STR1##中的那些[R.sub.1是具有1-12个C原子的烷基，R.sub.2是氢或具有1-12个C原子的烷基，R.sub.3是具有1-12个C原子的烷基，具有4-12个C原子的环烷基，具有7或8个C原子的芳基烷基，未取代或取代的芳基，吡啶基，呋喃基或噻吩基，R.sub.4是氢，具有1-12个C原子的烷基，具有4-12个C原子的环烷基，或未取代或取代的芳基，或R.sub.1和R.sub.2和/或R.sub.3和R.sub.4一起是具有3-11个C原子的亚烷基]，以及制备它们的过程。公式I的化合物例如可用于生产聚缩酸酐产品，特别是聚酰胺。它们也可用作环氧树脂的固化剂。
• Transparent copolyamide from 1,10-disubstituted C.sub.11 diamine
  申请人：Ciba-Geigy Corporation

  公开号：US04258176A1

  公开（公告）日：1981-03-24

  There are described transparent copolyamides which are obtained by reaction of a mixture (A) consisting of essentially stoichiometric amounts of a diamine ##STR1## and isophthalic acid or terephthalic acid, or a mixture of isophthalic acid and terephthalic acid, with a mixture (B) consisting of essentially stoichiometric amounts of a diamine ##STR2## and terephthalic acid or a mixture of terephthalic acid and isophthalic acid, or with a mixture (C) consisting of essentially stoichiometric amounts of a diamine ##STR3## and terephthalic acid or isophthalic acid or mixtures thereof, wherein R', R" and R.sub.1 to R.sub.11 have the meanings given in claim 1. The novel copolyamides are distinguished by good thermoplastic processing characteristics, by low water absorption and by good stability to hydrolysis, and are suitable for producing transparent moulded articles.

  描述了一种透明的共聚酰胺，该共聚酰胺是通过反应混合物(A)获得的，该混合物包含本质上等量的二胺##STR1##和苯二甲酸或对苯二甲酸，或对苯二甲酸和苯二甲酸的混合物，与本质上等量的二胺混合物(B)反应，该混合物包含苯二甲酸或对苯二甲酸或对苯二甲酸和苯二甲酸的混合物，或与本质上等量的混合物(C)反应，该混合物包含二胺##STR3##和苯二甲酸或对苯二甲酸或其混合物，其中R'，R"和R1到R11具有权利要求1中给出的含义。这种新型共聚酰胺具有良好的热塑性加工特性，低吸水性和良好的耐水解稳定性，适用于生产透明的模制品。
• Transparent polyamide from branched chain C.sub.11 diamine
  申请人：Giba-Geigy Corporation

  公开号：US04297480A1

  公开（公告）日：1981-10-27

  There are described transparent polyamides, and processes for producing them, which polyamides consist of recurring structural elements of the formula I ##STR1## or of recurring structural elements of the formula II ##STR2## [carbonyl groups in the structural elements (II) bound in the 1,3- and/or 1,4-position to the benzene nucleus, R.sub.1 =C.sub.1-12 -alkyl, R.sub.2 =H, C.sub.1-12 -alkyl, R.sub.3 =C.sub.1-12 -alkyl, C.sub.4-12 -cycloalkyl, C.sub.7-8 -aralkyl, unsubstituted or substituted aryl, R.sub.4 =H, C.sub.1-12 -alkyl, C.sub.4-12 -cycloalkyl, C.sub.7-8 -aralkyl, or unsubstituted or substituted aryl, or R.sub.3 /R.sub.4 together=C.sub.3-11 -alkylene, R.sub.5 /R.sub.6 independently of one another=hydrogen or methyl, and R.sub.7 /R.sub.8 together=C.sub.3-11 -alkylene]. The polyamides according to the invention are suitable for producing transparent moulded articles of the widest variety, and are distinguished in particular by low water absorption, high stability to hydrolysis, and/or good dimensional stability under the action of moisture or humidity.

  本发明描述了透明聚酰胺及其生产方法，该聚酰胺由公式I的重复结构单元或公式II的重复结构单元组成，其中结构单元（II）中的羰基基团在1,3-和/或1,4-位置与苯环相结合，R1=C1-12烷基，R2=H、C1-12烷基，R3=C1-12烷基、C4-12环烷基、C7-8芳基烷基、未取代或取代的芳基，R4=H、C1-12烷基、C4-12环烷基、C7-8芳基烷基或未取代或取代的芳基，或R3/R4共同=C3-11亚烷基，R5/R6独立地=氢或甲基，R7/R8共同=C3-11亚烷基。本发明的聚酰胺适用于制造各种透明成型品，特别是具有低吸水性、高水解稳定性和/或在潮湿或湿度作用下具有良好的尺寸稳定性。
• Substituted 1,11-diaminoundecanes, processes for producing them, and
  申请人：Ciba-Geigy Corporation

  公开号：US04460790A1

  公开（公告）日：1984-07-17

  There are described novel substituted 1,11-diaminoundecanes, particularly those of the formula ##STR1## [R.sub.1 is alkyl having 1-12 C atoms, R.sub.2 is hydrogen or alkyl having 1-12 C atoms, R.sub.3 is alkyl having 1-12 C atoms, cycloalkyl having 4-12 C atoms, aralkyl having 7 or 8 C atoms, unsubstituted or substituted aryl, pyridyl, furyl or thienyl, R.sub.4 is hydrogen, alkyl having 1-12 C atoms, cycloalkyl having 4-12 C atoms, or unsubstituted or substituted aryl, or R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 together are alkylene having 3-11 C atoms], and processes for prducing them. The compound of the formula I can be used for example for producing polycondensation products, particularly polyamides. They can be used also as curing agents for epoxide resins.

  描述了新型取代的1,11-二胺十一烷，特别是那些符合以下式的化合物[R.sub.1是具有1-12个碳原子的烷基，R.sub.2是氢或具有1-12个碳原子的烷基，R.sub.3是具有1-12个碳原子的烷基，环烷基具有4-12个碳原子，芳基具有7或8个碳原子，未取代或取代的芳基，吡啶基，呋喃基或噻吩基，R.sub.4是氢，具有1-12个碳原子的烷基，环烷基具有4-12个碳原子，或未取代或取代的芳基，或者R.sub.1和R.sub.2和/或R.sub.3和R.sub.4一起是具有3-11个碳原子的亚基]，以及生产它们的过程。式I的化合物可以用于生产聚缩酸酯产品，特别是聚酰胺。它们也可以用作环氧树脂的固化剂。
• Substituted 11-amino-undeca-4,8-dienal and 11-amino-undecanal
  申请人：Ciba-Geigy Corporation

  公开号：US04277621A1

  公开（公告）日：1981-07-07

  Novel substituted 11-amino-undeca-4,8-dienal and 11-amino-undecanal aldehyde-derivatives of the formulae Ia ##STR1## in which R.sub.1 to R.sub.6, Y and m are as defined in patent claim 1, and processes for their preparation are described. The compounds of the formulae Ia and Ib can be catalytically hydrogenated to novel 1,11-diaminoundecanes, which, in turn, can be used, for example, for the preparation of polycondensation products, in particular transparent polyamides, or as curing agents for epoxide resins.

  本文描述了式Ia和Ib的衍生物的制备方法，其中化合物为11-氨基十一烯-4,8-二醛和11-氨基十一醛，其化学式为：##STR1## 在此式中，R.sub.1到R.sub.6，Y和m的定义如专利要求1所述。公式Ia和Ib的化合物可以通过催化氢化制备新型1,11-二氨基十一烷，该化合物可以用于制备聚合物，特别是透明聚酰胺，或作为环氧树脂的固化剂。