2,6-Bis-(bromo-dimethyl-silanyl)-pyridine | 144601-28-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 2,6-Bis-(bromo-dimethyl-silanyl)-pyridine
• 英文别名: 2,6-Bis[bromo(dimethyl)silyl]pyridine；bromo-[6-[bromo(dimethyl)silyl]pyridin-2-yl]-dimethylsilane
• CAS: 144601-28-5
• 化学式: C₉H₁₅Br₂NSi₂
• 分子量: 353.204
• InChiKey: ICLITEZPQLLGDG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2,6-二溴吡啶 在 溴 、 magnesium 作用下， 以 四氢呋喃 、 四氯化碳 为溶剂， 反应 3.5h， 生成 2,6-Bis-(bromo-dimethyl-silanyl)-pyridine
  参考文献：
  名称：

  Polycylopentadienyls: Synthesis of arylsilylcyclopentadienyl compounds and their η5-complexes with tungsten

  摘要：

  A general route to arylsilylcyclopentadienyl compounds starting from 1,4-C6H4Br2, 2,6-C5NH3Br2 and 1,3,5-C6H3Br3 is described. The aryl bromides were treated with Mg/ClSiMe2H to give the aryldimethylsilanes 1,4-C6H4(SiMe2H)2, 2,6-C5NH3(SiMe2H)2, and 1,3,5-C6H3(SiMe2H)3 which after reaction with Cl2 or Br2 yielded the aryldimethylsilyl halides 1,4-C6H4(SiMe2Br)2, 2,6-C5NH3 (SiMe2Br)2, 1,3,5-C6H3(SiMe2X)3 (X = Br or Cl) in excellent yields. The halide can be replaced by various cyclopentadienides to give aryldimethylsilylcyclopentadienes of the general type 1,4-C6H4 (SiMe2CP)2 and 1,3,5-C6H3(SiMe2CP)3 (Cp = C5H5 (8,11), C5H3(t-C4H9)2 (9,12), C5HMe4 (10,13)). Compounds C6H5(SiMe2(C5H5)), 1,4-C6H4(SiMe2(C5H5))2 (8) and 1,3,5-C6H3(SiMe2(C5H5))3 (11) were in turn treated with NaH, (MeCN)3W(CO)3, and MeI to give the eta-5-bound complexes C6H5 (SiMe2(C5H4)W(CO)3Me) (14), 1,4-C6H4(SiMe2(C5H4)W(CO)3Me)2 (15), 1,3,5-C6H3(SiMe2(C5H4)-W(CO)3Me)3 (16), which contain up to three half-sandwich units within one molecule.

  DOI：

  10.1016/0022-328x(92)83456-r

文献信息

• Polycylopentadienyls: Synthesis of arylsilylcyclopentadienyl compounds and their η5-complexes with tungsten
  作者：Herbert Plenio

  DOI：10.1016/0022-328x(92)83456-r

  日期：1992.2

  A general route to arylsilylcyclopentadienyl compounds starting from 1,4-C6H4Br2, 2,6-C5NH3Br2 and 1,3,5-C6H3Br3 is described. The aryl bromides were treated with Mg/ClSiMe2H to give the aryldimethylsilanes 1,4-C6H4(SiMe2H)2, 2,6-C5NH3(SiMe2H)2, and 1,3,5-C6H3(SiMe2H)3 which after reaction with Cl2 or Br2 yielded the aryldimethylsilyl halides 1,4-C6H4(SiMe2Br)2, 2,6-C5NH3 (SiMe2Br)2, 1,3,5-C6H3(SiMe2X)3 (X = Br or Cl) in excellent yields. The halide can be replaced by various cyclopentadienides to give aryldimethylsilylcyclopentadienes of the general type 1,4-C6H4 (SiMe2CP)2 and 1,3,5-C6H3(SiMe2CP)3 (Cp = C5H5 (8,11), C5H3(t-C4H9)2 (9,12), C5HMe4 (10,13)). Compounds C6H5(SiMe2(C5H5)), 1,4-C6H4(SiMe2(C5H5))2 (8) and 1,3,5-C6H3(SiMe2(C5H5))3 (11) were in turn treated with NaH, (MeCN)3W(CO)3, and MeI to give the eta-5-bound complexes C6H5 (SiMe2(C5H4)W(CO)3Me) (14), 1,4-C6H4(SiMe2(C5H4)W(CO)3Me)2 (15), 1,3,5-C6H3(SiMe2(C5H4)-W(CO)3Me)3 (16), which contain up to three half-sandwich units within one molecule.