3-氨基丙基五甲基二硅氧烷 | 23029-21-2

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 中文名称: 3-氨基丙基五甲基二硅氧烷
• 中文别名: 噁唑-4-羧酸；4-恶唑羧酸
• 英文名称: γ-(aminopropyl)pentamethyldisiloxane
• 英文别名: (3-aminopropyl)pentamethyldisiloxane；γ-Aminopropyl-pentamethyl-disiloxan；(3-Amino-propyl)-pentamethyl-disiloxan；3-Aminopropylpentamethyldisiloxane；3-[dimethyl(trimethylsilyloxy)silyl]propan-1-amine
• CAS: 23029-21-2
• 化学式: C₈H₂₃NOSi₂
• mdl: MFCD01320927
• 分子量: 205.448
• InChiKey: QWFSPEQGWSIPLB-UHFFFAOYSA-N

物化性质

• 沸点：
  67-70 °C(Press: 6 Torr)
• 密度：
  0.843

计算性质

• 辛醇/水分配系数(LogP)：
  2.25
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  35.2
• 氢给体数：
  1
• 氢受体数：
  2

安全信息

• 海关编码：
  2921199090
• 储存条件：
  2-8°C，密封保存于干燥处。

反应信息

• 作为反应物：
  描述：

  3-氨基丙基五甲基二硅氧烷 、 酚酞 在 水 作用下， 以 邻二氯苯 、 甲苯 为溶剂， 反应 30.0h， 生成 N-(3-[(γ-aminopropyl)tetramethyldisiloxy]propyl)-3,3-bis(4-hydroxyphenyl)phthalimidine 、 N-[3-(hydroxydimethylsilyl)propyl]-3,3-bis(4-hydroxyphenyl)phthalimidine 、 1,3-bis([3,3-bis(4-hydroxyphenyl)phthalimidin-2-yl]propyl)tetramethyldisiloxane 、 N-[3-(pentamethyldisiloxy)propyl]-3,3-bis-(4-hydroxyphenyl)phthalimidine
  参考文献：
  名称：

  Reaction of γ-(aminopropyl)siloxanes with phenolphthalein as a route to new siloxane-containing phenols

  摘要：

  The reaction of gamma-aminopropylorganosiloxanes with phenolphthalein yields monomeric and oligomeric N-alkylsiloxy-3,3-bis(4-hydroxyphenyl)phthalimidines. Their structures and compositions were confirmed by IR and NMR spectroscopy and by HPLC-MS. Studies by GLC and MALDI mass spectrometry showed that the action of the amine and of the water released in the reaction leads to the rearrangement of the siloxane bond in the course of the synthesis with the formation of linear and cyclic carbofunctional oligomeric siloxanephenols and mixed oligophenolaminosiloxanes. The possibility of modification of epoxy resins with the synthesized oligomers was revealed.

  DOI：

  10.1134/s1070427214020141
• 作为产物：
  描述：

  五甲基二硅氧烷 在 dihydrogen hexachloroplatinate 水 作用下， 以 水 、 异丙醇 、 苯 为溶剂， 生成 3-氨基丙基五甲基二硅氧烷
  参考文献：
  名称：

  Addition reactions of linear siloxanes to allylamine

  摘要：

  DOI：

  10.1007/bf00922866

文献信息

• ZENBAYASHI, MICHIO;SATO, NORIA
  作者：ZENBAYASHI, MICHIO、SATO, NORIA

  DOI：——

  日期：——
• Addition reactions of linear siloxanes to allylamine
  作者：I. N. Lyashenko、N. S. Nametkin、T. I. Chernysheva

  DOI：10.1007/bf00922866

  日期：1969.5
• Reaction of γ-(aminopropyl)siloxanes with phenolphthalein as a route to new siloxane-containing phenols
  作者：D. O. Anashkin、I. M. Raigorodskii、V. M. Kopylov、V. A. Kovyazin、V. V. Boev、V. N. Sokolik

  DOI：10.1134/s1070427214020141

  日期：2014.2

  The reaction of gamma-aminopropylorganosiloxanes with phenolphthalein yields monomeric and oligomeric N-alkylsiloxy-3,3-bis(4-hydroxyphenyl)phthalimidines. Their structures and compositions were confirmed by IR and NMR spectroscopy and by HPLC-MS. Studies by GLC and MALDI mass spectrometry showed that the action of the amine and of the water released in the reaction leads to the rearrangement of the siloxane bond in the course of the synthesis with the formation of linear and cyclic carbofunctional oligomeric siloxanephenols and mixed oligophenolaminosiloxanes. The possibility of modification of epoxy resins with the synthesized oligomers was revealed.