N-Ethyl-N,N-dioctyloctan-1-aminium iodide | 89022-94-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-Ethyl-N,N-dioctyloctan-1-aminium iodide
• 英文别名: ethyl(trioctyl)azanium;iodide
• CAS: 89022-94-6
• 化学式: C26H56IN
• 分子量: 509.6
• InChiKey: NFOCMTBOEDRYTF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  5.91
• 重原子数：
  28
• 可旋转键数：
  22
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• HYDROCARBOXYLATION PROCESS
  申请人：Zoeller Joseph Robert

  公开号：US20070299280A1

  公开（公告）日：2007-12-27

  Disclosed is a hydrocarboxylation process for the production of carboxylic acid from olefins wherein an olefin, water, a Group VIII metal hydrocarboxylation catalyst, an onium salt compound are combined in a reaction zone and contacted with carbon monoxide under hydrocarboxylation conditions of pressure and temperature The process does not require or utilize the addition of a hydrogen halide or an alkyl halide exogenous or extraneous to the hydrocarboxylation process.

  揭示了一种从烯烃生产羧酸的羟基羧化过程，其中在反应区域中将烯烃、水、第VIII族金属羟基羧化催化剂和一个胞离子盐化合物结合，并在压力和温度的羟基羧化条件下与一氧化碳接触。该过程不需要或利用氢卤化物或烷基卤化物作为羟基羧化过程的外部添加物。
• PROCESS FOR PRODUCING POLYVALENT GLYCIDYL COMPOUND
  申请人：SHOWA DENKO K.K.

  公开号：US20170342042A1

  公开（公告）日：2017-11-30

  A polyvalent glycidyl compound is produced from a compound having one or more 2-alkenyl ether groups and two or more 2-alkenyl groups using a hydrogen peroxide aqueous solution as an oxidizing agent to oxidize the 2-alkenyl ether groups and the 2-alkenyl groups. A 2-alkenyl ether compound having two or more (un)substituted 2-alkenyl groups and one or more (un)substituted 2-alkenyl ether groups is oxidized using a hydrogen peroxide aqueous solution as an oxidizing agent in the presence of a tungsten compound and a quaternary ammonium salt as catalysts and of phosphoric acid as a co-catalyst, while controlling the pH of the reaction solution to 1.0-4.0 using an acid other than phosphoric acid. During the oxidation, the step of adding the hydrogen peroxide aqueous solution to the reaction solution and the step of adding the acid other than phosphoric acid thereto are alternately repeated at intervals two or more times.

  使用氢氧化物水溶液作为氧化剂，通过氧化2-烯基醚基团和2-烯基基团，从具有一个或多个2-烯基醚基团和两个或多个2-烯基基团的化合物中产生一种多价环氧化物化合物。在钨化合物和季铵盐作为催化剂和磷酸作为协同催化剂的存在下，在使用氢氧化物水溶液作为氧化剂的同时，氧化具有两个或更多个（未）取代的2-烯基基团和一个或多个（未）取代的2-烯基醚基团的2-烯基醚化合物，并使用除磷酸以外的酸将反应液的pH控制在1.0-4.0之间。在氧化过程中，将氢氧化物水溶液加入反应液和将酸加入其中的步骤交替重复两次或更多次的间隔时间内进行。
• Cycloaliphatic polyepoxy compounds and preparation thereof
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP1873149A1

  公开（公告）日：2008-01-02

  Is disclosed a cycloaliphatic polyepoxy compound represented by following Formula (1): wherein Y represents a linkage group or a single bond; and HAS each represent hydrogen atom at the junction between cyclohexane ring and oxirane ring, and the cyclohexane rings may each further have one or more substituents in addition to the groups shown in the formula. The cycloaliphatic polyepoxy compound contains stereoisomers in such proportions as to have a ratio A/B of 1.8 or more, wherein "A" and "B" are integrated intensities of signals of protons at the junction between cyclohexane ring and oxirane ring as determined by 1H-NMR spectroscopy of the compound, in which "A" represents the integrated intensity of a signal observed at a lower magnetic field, and "B" represents the integrated intensity of a signal observed at a higher magnetic field.

  公开了一种由下式（1）表示的环状脂肪族多环氧化合物：其中，Y表示连接基团或单键；HAS分别表示在环己烷环和环氧环之间的连接处的氢原子，环己烷环除了式中所示的基团外，还可以有一个或多个取代基。所述环状脂肪族多环氧化合物包含立体异构体，其比例为A/B≥1.8，其中“A”和“B”是化合物的1H-NMR光谱测定下在环己烷环和环氧环之间的连接处的质子信号的积分强度，“A”表示在较低磁场下观察到的信号的积分强度，“B”表示在较高磁场下观察到的信号的积分强度。
• RECOVERY METHOD AND REUSE METHOD OF OXO ACID CATALYST
  申请人：DAICEL CORPORATION

  公开号：US20160074856A1

  公开（公告）日：2016-03-17

  Provided is a method for easily and efficiently recovering an oxoacid catalyst without deterioration in reaction product yield and catalytic activity, where the oxoacid catalyst has been used in a reaction for oxidizing an organic compound with hydrogen peroxide, also provided is a method for producing an oxide in which an organic compound is oxidized with hydrogen peroxide using the oxoacid catalyst recovered by the method, to yield the corresponding oxide. A method according to the present invention recovers an oxoacid catalyst used in a reaction for oxidizing an organic compound with hydrogen peroxide in an aqueous/organic solvent two-phase system. The method includes Step 1 in which the pH in the reaction system is adjusted to 5.0 or higher so as to transfer the oxoacid catalyst to the aqueous phase, and the organic phase is removed.

  提供了一种方法，可以轻松高效地回收氧酸催化剂，而不会降低反应产物收率和催化活性。该氧酸催化剂已用于氧化有机化合物的反应中，使用过氧化氢。同时提供了一种方法，使用通过该方法回收的氧酸催化剂，将有机化合物与过氧化氢氧化，以产生相应的氧化物。本发明提供的方法在水/有机溶剂两相体系中回收用于氧化有机化合物的氧酸催化剂。该方法包括步骤1，将反应体系中的pH调整至5.0或更高，以将氧酸催化剂转移至水相，并去除有机相。
• Process for producing 1-hydrocarbyl mercaptans
  申请人：PHILLIPS PETROLEUM COMPANY

  公开号：EP0268261A1

  公开（公告）日：1988-05-25

  A process is disclosed for producing 1-hydrocarbyl mercaptans which comprises reacting a 1-hydrocarbyl halide with an alkali hydrogen sulfide or an ammonium hydrogen sulfide in the presence of a quaternary ammonium halide, which serves as a phase transfer catalyst.

  本发明公开了一种生产 1-氢羰基硫醇的工艺，该工艺包括在作为相转移催化剂的季铵盐化物存在下，使 1-氢羰基卤化物与碱硫化氢或硫化氢铵反应。