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2-Anthracen-9-yl-6-[[2,4,6-tris[3,5-bis(trifluoromethyl)phenyl]phenyl]iminomethyl]phenol | 1448300-02-4

中文名称
——
中文别名
——
英文名称
2-Anthracen-9-yl-6-[[2,4,6-tris[3,5-bis(trifluoromethyl)phenyl]phenyl]iminomethyl]phenol
英文别名
——
2-Anthracen-9-yl-6-[[2,4,6-tris[3,5-bis(trifluoromethyl)phenyl]phenyl]iminomethyl]phenol化学式
CAS
1448300-02-4
化学式
C51H25F18NO
mdl
——
分子量
1009.74
InChiKey
JBFDOCQANOGSHY-UHFFFAOYSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    17.2
  • 重原子数:
    71
  • 可旋转键数:
    6
  • 环数:
    8.0
  • sp3杂化的碳原子比例:
    0.12
  • 拓扑面积:
    32.6
  • 氢给体数:
    1
  • 氢受体数:
    20

上下游信息

  • 上游原料
    中文名称 英文名称 CAS号 化学式 分子量

反应信息

  • 作为反应物:
    描述:
    dimethyl(tetramethylethylenediamine)nickel(II) 、 2-Anthracen-9-yl-6-[[2,4,6-tris[3,5-bis(trifluoromethyl)phenyl]phenyl]iminomethyl]phenol 、 trisodium tris(3-sulfophenyl)phosphine 、 N,N-二甲基甲酰胺 反应 0.83h, 以81%的产率得到[[(2,4,6-(3,5-(CF3)2C6H3)3-C6H2)-N=C(H)-(3-(9-anthryl)-2-O-C6H3)-κ2-N,O]Ni(CH3)(tri(sodiumphenylsulfonate)phosphine)]*DMF
    参考文献:
    名称:
    Ideal Polyethylene Nanocrystals
    摘要:
    The water-soluble catalyst precursor [[(2,4,6-(3,5-(CF3)(2)C6H3)(3)-C6H2)-N=C(H)-(3-(9-anthry1)-2-O-C61-13)-kappa(2)-N,0]Ni(CH3)(TPPTS)] (TPPTS = tri-(sodiumphenylsulfonate)phosphine) polymerizes ethylene to aqueous dispersions of highly ordered nanoscale crystals (crystallinity chi(DSC) >= 9096) of strictly linear polyethylene (<0.7 methyl-branches/1000 carbon atoms, Mu = 4.2 x 105 g mol(-1)). SAXS in combination with cryo-TEM confirms this unusually high degree of order (chi(SAXS) = 82%) and shows the nanoparticles to possess a very thin amorphous layer on the crystalline lamella, just sufficient to accommodate a loop, but likely no entanglements. This ideal chain-folded structure is corroborated by annealing studies on the aqueous-dispersed nanoparticles, which show that the chain can move through the crystal as evidenced by lamella thickening without disturbing the crystalline order as concluded from an unaltered low thickness of the amorphous layers. These ideal chain-folded polyethylene nanocrystals arise from the crystallization in the confined environment of a nanoparticle and a deposition of the growing polymer chain on the crystal growth front as the chain is formed by the catalyst.
    DOI:
    10.1021/ja4052334
  • 作为产物:
    描述:
    5'-(3,5-bis(trifluoromethyl)phenyl)-3,3'',5,5''-tetrakis(trifluoromethyl)-[1,1':3',1''-terphenyl]-2'-amine3-蒽-9-基-2-羟基苯甲醛对甲苯磺酸 作用下, 以 甲醇 为溶剂, 反应 16.0h, 以72%的产率得到2-Anthracen-9-yl-6-[[2,4,6-tris[3,5-bis(trifluoromethyl)phenyl]phenyl]iminomethyl]phenol
    参考文献:
    名称:
    Ideal Polyethylene Nanocrystals
    摘要:
    The water-soluble catalyst precursor [[(2,4,6-(3,5-(CF3)(2)C6H3)(3)-C6H2)-N=C(H)-(3-(9-anthry1)-2-O-C61-13)-kappa(2)-N,0]Ni(CH3)(TPPTS)] (TPPTS = tri-(sodiumphenylsulfonate)phosphine) polymerizes ethylene to aqueous dispersions of highly ordered nanoscale crystals (crystallinity chi(DSC) >= 9096) of strictly linear polyethylene (<0.7 methyl-branches/1000 carbon atoms, Mu = 4.2 x 105 g mol(-1)). SAXS in combination with cryo-TEM confirms this unusually high degree of order (chi(SAXS) = 82%) and shows the nanoparticles to possess a very thin amorphous layer on the crystalline lamella, just sufficient to accommodate a loop, but likely no entanglements. This ideal chain-folded structure is corroborated by annealing studies on the aqueous-dispersed nanoparticles, which show that the chain can move through the crystal as evidenced by lamella thickening without disturbing the crystalline order as concluded from an unaltered low thickness of the amorphous layers. These ideal chain-folded polyethylene nanocrystals arise from the crystallization in the confined environment of a nanoparticle and a deposition of the growing polymer chain on the crystal growth front as the chain is formed by the catalyst.
    DOI:
    10.1021/ja4052334
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同类化合物

(2R,3R)-4-(蒽-9-基)-3-(叔丁基)-2-甲基-2,3-二氢苯并[d][1,3]氧杂磷杂环戊烯 金不换萘酚 金不换素 蒽,9,10-二[4-(2,2-二苯基乙烯基)苯基]- 萘并[2,3-c]呋喃-1,3-二酮,6-甲氧基-4-(4-甲氧苯基)- 萘并[2,3-c]呋喃-1(3H)-酮,7-羟基-4-(3-甲氧苯基)- 萘并[2,3-c]呋喃-1(3H)-酮,4-(2-氟苯基)-7-(苯基甲氧基)- 萘,1-氯-2-乙基-3-甲基-4-苯基- 苯氧基-9苯基-10蒽 苯基-(10-苯基蒽-9-基)甲酮 红荧烯 甲基7-苯基二苯并(A,J)蒽-14-羧酸酯 甲基10-苯基-9-蒽羧酸酯 爵床脂素 B 爵床脂素 A 木酚素J1(P) 昔土米霉素 新爵床素 B 拒食胺 大麻酰胺 地蒽酚10,10'-二聚体 四去氢鬼臼毒素 叶下珠醇抑制剂A 双(4-(蒽-9-基)苯基)甲酮 二甲基4-(3,4-二甲氧苯基)-1-羟基-5,6,7-三甲氧基萘-2,3-二甲酸基酯 二叶草素 乙酸-(2-甲基-3,4-二苯基-[1]萘基酯) [4-(3,10-二羟基蒽-9-基)苯基]乙酸乙酸酯 [4-(10-羟基蒽-9-基)苯基]乙酸乙酸酯 [2-甲氧基-10-(4-甲氧基苯基)蒽-9-基]乙酸酯 [10-羟基-5-(10-羟基-7,9-二甲氧基-3-甲基-3,4-二氢-1H-苯并[g]异苯并吡喃-5-基)-7,9-二甲氧基-3-甲基-3,4-二氢-1H-苯并[g]异苯并吡喃-4-基]乙酸酯 [10-(9,9-二甲基芴-2-基)蒽-9-基]硼酸 [10-(4-叔丁基苯基)蒽-9-基]硼酸 [(9,10-二苯基-[2]蒽基)-苯基-亚甲基]-琥珀酸 B-[10-(4-苯基-1-萘基)-9-蒽基]硼酸 B-(9,10-二苯基-2-蒽)硼酸 9.10-二(3',5'-二羧基苯基)蒽 9-萘-1-基-10-(4-苯基苯基)蒽 9-苯基蒽 9-苯基-10-苯乙炔基菲 9-苯基-10-硝基蒽 9-苯基-10-(苯基乙炔基)蒽 9-苯基-10-(4-三苯胺)蒽 9-苯基-1,2,3,4-四氢蒽 9-苄基-10-苯基蒽 9-羟基-10-甲氧基-5-(3,4,5-三甲氧基苯基)-8H-[2]苯并呋喃并[6,5-f][1,3]苯并二氧戊环-6-酮 9-碘-10-(10-碘蒽-9-基)蒽 9-甲氧基甲基-10-苯基蒽 9-甲氧基-10-苯基蒽 9-甲基-10-苯基菲