N8,N8,3-Trimethyl-2,8-phenazinediamine sulfate (1:1) | 35836-04-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: N8,N8,3-Trimethyl-2,8-phenazinediamine sulfate (1:1)
• 英文别名: sulfuric acid;8-N,8-N,3-trimethylphenazine-2,8-diamine
• CAS: 35836-04-5
• 化学式: C15H18N4O4S
• 分子量: 350.4
• InChiKey: CJEIMBWGALFTAA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.16
• 重原子数：
  24
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  142
• 氢给体数：
  3
• 氢受体数：
  7

文献信息

• IMPROVED METHOD OF PRODUCING POLYMERIC PHENAZONIUM COMPOUNDS
  申请人：MacDermid Acumen, Inc.

  公开号：EP2619244A1

  公开（公告）日：2013-07-31
• Method of Producing Polymeric Phenazonium Compounds
  申请人：Krol Andrew M.

  公开号：US20120077956A1

  公开（公告）日：2012-03-29

  A process of making a polymeric phenazonium compound having the general formula: wherein R 1 , R 2 , R 4 , R 5 , R 6 , R 8 and R 9 are the same or different, and represent hydrogen, a low alkyl or a substituted aryl, R 3 starts with NH 2 and is diazotized followed by polymerization, R 5 and R 8 may alternatively represent monomeric or polymeric phenazonium radicals, R 7 with its substituent group is a substituted amine, with R X and R Y representing any combination of CH 3 , C 2 H 5 , and hydrogen, except that R X and R Y cannot both be hydrogen, A is an acid radical, and n is an integer from 2 to 100, preferably from 2 to 20 is described. The polymeric phenazonium compound is usable in as an additive in a metal plating bath. The method includes the steps of: a) dissolving an effective amount of an amino compound in a formic acid solution; b) adding a nitrite salt to diazotize the amino compound; and c) adding sulfamic acid to neutralize any excess nitrous acid that may be formed in step b), whereby a polymeric phenazonium compound is produced.
• US8735580B2
  申请人：——

  公开号：US8735580B2

  公开（公告）日：2014-05-27
• US9040700B2
  申请人：——

  公开号：US9040700B2

  公开（公告）日：2015-05-26
• [EN] IMPROVED METHOD OF PRODUCING POLYMERIC PHENAZONIUM COMPOUNDS<br/>[FR] PROCÉDÉ AMÉLIORÉ DE PRODUCTION DE COMPOSÉS POLYMÈRES DE PHÉNAZONIUM
  申请人：MACDERMID ACUMEN INC

  公开号：WO2012040417A1

  公开（公告）日：2012-03-29

  A process of making a polymeric phenazonium compound having the general formula: wherein R1, R2, R4, R5, R6, R8 and R9 are the same or different, and represent hydrogen, a low alkyl or a substituted aryl, R3 stalls as NH2 and is diazotized followed by polymerization, R5 and R8 may alternatively represent monomeric or polymeric phenazonium radicals, R7 is a carbon in the aromatic ring, and wherein RX-N-RY represents a substituted amine, and Rx and Ry represent any combination of CH3, C2H5, and hydrogen, except that Rx and RY cannot both be hydrogen, A is an acid radical, and n is an integer from 2 to 100. The polymeric phenazonium compound is usable in as an additive in a metal plating bath. The method includes the steps of: a) dissolving an effective amount of an amino compound in a formic acid solution; b) adding a nitrite salt to diazotize the amino compound; and c) adding sulfamic acid to neutralize any excess nitrous acid that may be fonned in step b), whereby a polymeric phenazonium compound is produced.