TiCl4(azobisisobutyronitrile) | 146250-11-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: TiCl4(azobisisobutyronitrile)
• CAS: 146250-11-5
• 化学式: C₈H₁₂Cl₄N₄Ti
• 分子量: 353.902
• InChiKey: IVOZUCXQFBOKMR-DMDFFLOWSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  TiCl4(azobisisobutyronitrile) 以 solid 为溶剂， 生成 TiCl₄(dinitrile of tetramethyladipic acid)
  参考文献：
  名称：

  Synthesis and reactivity of metal-containing monomers. 21. Synthesis of TiCl4 and VCl4 complexes with azobisisobutyronitrile and studies of their thermal decomposition

  摘要：

  Complexes of azobisisobutyronitrile (AIBN) with titanium tetrachloride and vanadium tetrachloride have been synthesized and characterized. It was demonstrated that Ti(IV) and V(IV) form equimolar complexes with AIBN, with nitrile ligands located in cis positions in the coordination spheres of metal atoms. Kinetics of thermal decomposition of free and complexed AIBN were studied and compared. The gas evolution rate was measured in the presence of tetrabutoxytitanium, which does not react with AIBN. It was demonstrated that complexing leads to a marked increase of the rate constant of AIBN thermal decomposition.

  DOI：

  10.1007/bf00864330
• 作为产物：
  描述：

  2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile 、 四氯化钛 以 甲苯 为溶剂， 生成 TiCl4(azobisisobutyronitrile)
  参考文献：
  名称：

  Synthesis and reactivity of metal-containing monomers. 21. Synthesis of TiCl4 and VCl4 complexes with azobisisobutyronitrile and studies of their thermal decomposition

  摘要：

  Complexes of azobisisobutyronitrile (AIBN) with titanium tetrachloride and vanadium tetrachloride have been synthesized and characterized. It was demonstrated that Ti(IV) and V(IV) form equimolar complexes with AIBN, with nitrile ligands located in cis positions in the coordination spheres of metal atoms. Kinetics of thermal decomposition of free and complexed AIBN were studied and compared. The gas evolution rate was measured in the presence of tetrabutoxytitanium, which does not react with AIBN. It was demonstrated that complexing leads to a marked increase of the rate constant of AIBN thermal decomposition.

  DOI：

  10.1007/bf00864330