Acetic acid 1-fluoro-6-(4-propyl-cyclohexyl)-naphthalen-2-yl ester | 370568-65-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: Acetic acid 1-fluoro-6-(4-propyl-cyclohexyl)-naphthalen-2-yl ester
• CAS: 370568-65-3
• 化学式: C₂₁H₂₅FO₂
• 分子量: 328.427
• InChiKey: JBPGOMMGNQFMQU-WKILWMFISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.98
• 重原子数：
  24.0
• 可旋转键数：
  4.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  26.3
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  Acetic acid 1-fluoro-6-(4-propyl-cyclohexyl)-naphthalen-2-yl ester 在 palladium on activated charcoal 四(三苯基膦)钯 、 氢气 作用下， 生成
  参考文献：
  名称：

  Design, Synthesis and Physical Properties of New Liquid Crystal Materials Having a Fluoro-Substituted Tetrahydronaphthalene Structure for Active Matrix LCD

  摘要：

  Liquid crystal materials having a fluoro-substituted tetralhydro-naphthalene structure were designed for active matrix LCD. 6-Aryl-5-fluoro-1,2,3,4-tetrahydronaphthalenes and 5,6-difluro-1,2,3,4-tetrahydronaphthalenes were prepared by regioselective fluorination and hydrogenation of 2-naphthols. 6-Aryl-5,7-difluoro-1,2,3,4-tetrahydronaphthalenes were synthesized from 5,7-difluoro-1,2,3,4-tetrahydronaphthalene-2-one. The liquid crystal mixture containing these compounds with very good co-solubility exhibits a wide nematic temperature range with low melting point and very large value of dielectric anisotropy. From these results these compounds are useful for design. of new liquid crystal mixtures for TFT-displays.

  DOI：

  10.1080/15421400490434973
• 作为产物：
  描述：

  6-(trans-4-Propylcyclohexyl)-2-naphthol 在 N,N’-difluoro-2,2’-bipyridinium bis(tetrafluoroborate) 作用下， 生成 Acetic acid 1-fluoro-6-(4-propyl-cyclohexyl)-naphthalen-2-yl ester
  参考文献：
  名称：

  Design, Synthesis and Physical Properties of New Liquid Crystal Materials Having a Fluoro-Substituted Tetrahydronaphthalene Structure for Active Matrix LCD

  摘要：

  Liquid crystal materials having a fluoro-substituted tetralhydro-naphthalene structure were designed for active matrix LCD. 6-Aryl-5-fluoro-1,2,3,4-tetrahydronaphthalenes and 5,6-difluro-1,2,3,4-tetrahydronaphthalenes were prepared by regioselective fluorination and hydrogenation of 2-naphthols. 6-Aryl-5,7-difluoro-1,2,3,4-tetrahydronaphthalenes were synthesized from 5,7-difluoro-1,2,3,4-tetrahydronaphthalene-2-one. The liquid crystal mixture containing these compounds with very good co-solubility exhibits a wide nematic temperature range with low melting point and very large value of dielectric anisotropy. From these results these compounds are useful for design. of new liquid crystal mixtures for TFT-displays.

  DOI：

  10.1080/15421400490434973