| 300661-90-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• CAS: 300661-90-9
• 化学式: C₁₂H₃₀LaN₅O₁₈P₂
• 分子量: 733.246
• InChiKey: RUTQMYBLSHTLFH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  diethyl 1-(hydroxyimino)ethylphosphonate 、 lanthanum(III) nitrate 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Synthesis of the first lanthanide complexes of dialkyl α-hydroxyiminophosphonates; ambivalent ligand bonding in the Pr^IIIand Nd^IIIcomplexes of diisopropyl α-hydroxyiminopropylphosphonate (L¹), [PrL¹₃Cl₃] and [NdL¹₂(NO₃)₃(H₂O)]

  摘要：

  Lanthanide complexes of dialkyl alpha-hydroxyiminophosphonates (RO)2P(O)C(R')N(OH) (L1-L3), where R = Et or Pr(i) and R' = Me or Et, have been prepared for the first time; the crystal structures of two complexes of L1 (R = Pr(i), R' = Et) have been determined, showing nine-co-ordination geometry in both cases with asymmetric bidentate ligands in [PrL13Cl3] and monodentate bonding in [NdL21(NO3)3(H2O)] demonstrating that the ambivalent nature of the new ligands allow formation of neutral complexes.

  DOI：

  10.1039/dt9940002335