[Ru(III)(2,2',6',2''-terpyridine)(picolinate)(HO)](1+) | 921612-07-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯并吡啶类
• 英文名称: [Ru(III)(2,2',6',2''-terpyridine)(picolinate)(HO)](1+)
• 英文别名: [Ru(III)(tpy)(pic)(HO)](1+)；[Ru(III)(tpy)(pic)OH](1+)；[Ru(III)(2,2',6',2''-terpyridine)(picolinate)(OH)](1+)；[Ru(III)(OH)(2,2':6',2''-terpyridine)(picolinato)](1+)
• CAS: 921612-07-9
• 化学式: C₂₁H₁₆N₄O₃Ru
• 分子量: 473.453
• InChiKey: GSSDESDQXGDOCO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [Ru(II)(tpy)(pic)H2O]ClO4 在 NaClO₄ 作用下， 以 水 为溶剂， 生成 [Ru(III)(2,2',6',2''-terpyridine)(picolinate)(HO)](1+)
  参考文献：
  名称：

  Synthesis, characterization and reactivity of a novel ruthenium(II) complex containing polypyridyl ligand

  摘要：

  The [Ru-II(trpy)(pic)(H2O)](+) (1) was synthesized and characterized by analytical, spectral (UV-Vis and IR), molar conductivity, magnetic moment and electrochemical studies. Complex 1 catalyzes the epoxidation of styrene and stilbenes in presence of tert-butyl hydroperoxide (t-BuOOH) in dichloromethane at room temperature. No epoxide formation was observed in presence of the radical trapping agent (benzoquinone). A mechanism involving formation of [Ru-O(t-Bu)-O] type of radicaloid intermediate as an active intermediate responsible for epoxide formation is proposed for the catalytic epoxidation process. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.08.005

文献信息

• Llobet, Antoni; Doppelt, Pascal; Meyer, Thomas J., Inorganic Chemistry, 1988, vol. 27, # 3, p. 514 - 520
  作者：Llobet, Antoni、Doppelt, Pascal、Meyer, Thomas J.

  DOI：——

  日期：——