(2,9-dimesityl-1,10-phenanthroline)(1,10-phenanthroline)copper(I) | 878269-60-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: (2,9-dimesityl-1,10-phenanthroline)(1,10-phenanthroline)copper(I)
• CAS: 878269-60-4
• 化学式: C₄₂H₃₆CuN₄
• 分子量: 660.321
• InChiKey: BJAARTRNZGCRQS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 以 硝基甲烷 、 氘代乙腈 为溶剂， 反应 2.0h， 生成 (2,9-dimesityl-1,10-phenanthroline)(1,10-phenanthroline)copper(I) 、
  参考文献：
  名称：

  Spontaneous and catalytic fusion of supramolecules

  摘要：

  利用补全和整合自排序原理，实现了超分子到超分子的简洁转化，包括将一个 3 分量的矩形和一个 2 分量的等边三角形融合成一个 5 分量的正三角形。自发转化过程在 25 °C 下需要 15 小时，而催化转化只需 1 小时即可完成。

  DOI：

  10.1039/c2cc35036j

文献信息

• From 2-Fold Completive to Integrative Self-Sorting: A Five-Component Supramolecular Trapezoid
  作者：Kingsuk Mahata、Michael Schmittel

  DOI：10.1021/ja907185k

  日期：2009.11.18

  The amalgamation of two incomplete self-sorting processes into a process that makes quantitative use of all members of the library is described by 2-fold completive self-sorting. Toward this goal, individual metal-ligand binding scenarios were optimized for high thermodynamic stability and best selectivity, by screening a variety of factors, such as steric and electronic effects, pi-pi interactions, and metal-ion specifics. Using optimized, heteroleptic metal-ligand binding motifs, a library of four different ligands (1, 2, 3, 4) and two different metal ions (Zn2+, Cu+) was set up to assess 2-fold completive self-sorting. Out of 20 different combinations, the self-sorting library ended up with only two metal-ligand complexes in basically quantitative yield. To demonstrate the value of 2-fold completive self-sorting for the formation of nanostructures, the optimized, highly selective binding motifs were implemented into three polyfunctional ligands. Their integrative self-sorting in the presence of Zn2+ and Cu+ led to the clean formation of the supramolecular trapezoid T, a simple but still unknown supramolecular architecture. The dynamic trapezoid T consists of three different ligands with four different donor-acceptor interactions. Its structure was established by H-1 NMR spectroscopy, electrospray ionization mass spectroscopy, and differential pulse voltammetry (DPV) and by exclusion of alternative structures.