3-[(2-Methylpropan-2-yl)oxy]-2,4-dioxa-3-phosphatricyclo[7.3.1.05,13]trideca-1(12),5,7,9(13),10-pentaene | 110107-35-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 3-[(2-Methylpropan-2-yl)oxy]-2,4-dioxa-3-phosphatricyclo[7.3.1.05,13]trideca-1(12),5,7,9(13),10-pentaene
• CAS: 110107-35-2
• 化学式: C₁₄H₁₅O₃P
• 分子量: 262.245
• InChiKey: GCCVUZYHCNXGFA-UHFFFAOYSA-N

物化性质

• 沸点：
  321.6±15.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-[(2-Methylpropan-2-yl)oxy]-2,4-dioxa-3-phosphatricyclo[7.3.1.05,13]trideca-1(12),5,7,9(13),10-pentaene 生成 3-[(2-methylpropan-2-yl)oxy]-2,4-dioxa-3λ5-phosphatricyclo[7.3.1.05,13]trideca-1(12),5,7,9(13),10-pentaene 3-oxide
  参考文献：
  名称：

  KONIG, T.;HABICHER, W. D.;SCHWETLICK, K., J. PRAKT. CHEM., 331,(1989) N, C. 913-922

  摘要：

  DOI：
• 作为产物：
  描述：

  二-叔-丁基过氧草酸酯 、 3-(2,6-ditert-butyl-4-methylphenoxy)-2,4-dioxa-3-phosphatricyclo[7.3.1.05,13]trideca-1(12),5,7,9(13),10-pentaene 以 氯苯 为溶剂， 以17%的产率得到3-[(2-Methylpropan-2-yl)oxy]-2,4-dioxa-3-phosphatricyclo[7.3.1.05,13]trideca-1(12),5,7,9(13),10-pentaene
  参考文献：
  名称：

  Schwetlick, Klaus; Koenig, Thomas; Rueger, Claus, Zeitschrift fur Chemie, 1986, vol. 26, # 10, p. 360 - 366

  摘要：

  DOI：

文献信息

• SCHWETLICK, KLAUS;KONIG, THOMAS;RUGER, CLAUS;PIONTECK, JURGEN, Z. CHEM., 26,(1986) N 10, 360-366
  作者：SCHWETLICK, KLAUS、KONIG, THOMAS、RUGER, CLAUS、PIONTECK, JURGEN

  DOI：——

  日期：——
• CATALYSTS FOR EPOXIDE CARBONYLATION
  申请人：Novomer, Inc.

  公开号：US20170080409A1

  公开（公告）日：2017-03-23

  The present invention encompasses catalysts for the carbonylation of heterocycles such as ethylene oxide, as well as methods for their use. The catalysts feature Lewis acidic metal complexes having one or more tethered metal-coordinating groups in combination with at least one metal carbonyl species. In preferred embodiments, the inventive catalysts have improved stability when subjected to product separation conditions in continuous ethylene oxide carbonylation processes.