2-ethyl-6-methylcyclohexylamine | 24217-21-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2-ethyl-6-methylcyclohexylamine
• 英文别名: 2-Methyl-6-athylcyclohexylamine；2-ethyl-6-methylcyclohexan-1-amine
• CAS: 24217-21-8
• 化学式: C₉H₁₉N
• mdl: MFCD19205363
• 分子量: 141.257
• InChiKey: AHKHWYDFBOFLHS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (2R)-2-[[(2S)-4-methoxy-4-oxo-2-(phenylmethoxycarbonylamino)butanoyl]amino]propanoic acid 、 2-ethyl-6-methylcyclohexylamine 以50%的产率得到
  参考文献：
  名称：

  BRENNAN, THOMAS M.;HENDRICK, MICHAEL F.

  摘要：

  DOI：

文献信息

• FLUORINATED SULFONATE ESTERS OF ARYL KETONES FOR NON-IONIC PHOTO-ACID GENERATORS
  申请人：International Business Machines Corporation

  公开号：US20180046077A1

  公开（公告）日：2018-02-15

  Non-ionic photo-acid generating (PAG) compounds were prepared that contain an aryl ketone group having a perfluorinated substituent alpha to the ketone carbonyl. The non-polymeric PAGs release a sulfonic acid when exposed to high energy radiation such as deep UV or extreme UV light. The photo-generated sulfonic acid has a low diffusion rate in an exposed resist layer subjected to a post-exposure bake (PEB) at 100° C. to 150° C., resulting in formation of good line patterns after development. At higher temperatures, the PAGs can also undergo a thermal reaction to form a sulfonic acid. The perfluorinated substituent provides improved thermal stability and hydrolytic/nucleophilic stability.

  非离子型光生酸(PAG)化合物被制备出来，它们含有一个含有全氟取代基的芳酮基团，该取代基位于酮羰基的α位置。这些非聚合PAGs在暴露于高能辐射，如深紫外或极紫外光时，会释放出磺酸。在100°C至150°C的后曝光烘烤(PEB)下，光生成的磺酸在暴露的抵抗层中具有较低的扩散速率，从而在开发后形成良好的线条图案。在较高温度下，PAGs也可以通过热反应形成磺酸。全氟取代基提供了改善的热稳定性和水解/亲核稳定性。
• NON-IONIC LOW DIFFUSING PHOTO-ACID GENERATORS
  申请人：International Business Machines Corporation

  公开号：US20180044284A1

  公开（公告）日：2018-02-15

  Non-ionic photo-acid generating (PAG) compounds were prepared that contain an aryl ketone group. The disclosed non-polymeric PAGs release a strong sulfonic acid when exposed to high energy radiation such as deep UV or extreme UV light. The photo-generated sulfonic acid has a low diffusion rate in an exposed resist layer subjected to a post-exposure bake (PEB) at 100° C. to 150° C., resulting in formation of good line patterns after development. At higher temperatures, the PAGs undergo a thermal reaction to form a sulfonic acid.

  制备了含芳基酮基团的非离子光酸发生（PAG）化合物。揭示的非聚合物PAG在暴露于高能辐射（如深紫外或极紫外光）时释放出强磺酸。光生磺酸在经过后曝光烘烤（PEB）处理（在100°C至150°C下）的受暴露光阻层中具有低扩散速率，从而在显影后形成良好的线条图案。在较高温度下，PAG会发生热反应形成磺酸。
• Verfahren zur Herstellung von 2,6-Dialkylcyclohexylaminen
  申请人：CIBA-GEIGY AG

  公开号：EP0022751A1

  公开（公告）日：1981-01-21

  Verfahren zur Herstellung von 2,6-Dialkylcyclohexylaminen, z.B. 2,6-Dimethylcyclohexylamin, durch Umsetzung eines 2,6-Dialkylphenols, z.B. 2,6-Dimethylphenol, mit Ammoniak in Gegenwart eines Wasserstoffübertragungskatalysators und Wasserstoff bei erhöhter Temperatur und erhöhtem Druck.

  一种制备 2,6-二烷基环己胺，如 2,6-二甲基环己胺的工艺，在氢转移催化剂和氢的存在下，在高温高压下使 2,6-二烷基酚，如 2,6-二甲基苯酚与氨反应。
• Branched amides of L-aspartyl-D-amino acid dipeptides and compositions thereof
  申请人：PFIZER INC.

  公开号：EP0034876A2

  公开（公告）日：1981-09-02

  Amides of L-aspartyl-D-amino acid dipeptides of the formula and physiologically acceptable cationic and acid addition salts thereof wherein Ra is methyl, ethyl, n-propyl or isopropyl and R is a branched aliphatic, alicyclic or heterocyclic member which is branched at the alpha carbon atom (the carbon atom bearing the amide nitrogen atom) and also branched again at one or both of the beta carbon atoms, are potent sweeteners which are free from undesirable flavour qualities and of high stability in conventional food processing. Sweetening compositions and sweetened edible compositions of such amides are also claimed

  式中 L-天冬氨酰-D-氨基酸二肽的酰胺类 及其生理上可接受的阳离子盐和酸加成盐，其中 Ra 为甲基、乙基、正丙基或异丙基，R 为支链脂环族、脂环族或杂环族成员，该成员在 α 碳原子（含酰胺氮原子的碳原子）上有支链，在一个或两个β碳原子上也有支链。这种酰胺的甜味组合物和甜味可食用组合物也已申请专利。
• COMPOUND FOR AN ORGANIC PHOTOELECTRIC ELEMENT, AND AN ORGANIC PHOTOELECTRIC ELEMENT COMPRISING THE SAME
  申请人：CHEIL INDUSTRIES INC.

  公开号：EP2452997A2

  公开（公告）日：2012-05-16

  Provided are a compound for an organic photoelectric device represented by Chemical Formula 1 and an organic photoelectric device including the same. The structure of Chemical Formula 1 is described in the specification. The compound for an organic photoelectric device is used to form an organic thin layer for an organic photoelectric device and thus, provides an organic photoelectric device and a display device with high luminous efficiency at a low driving voltage and improved life-span.

  本发明提供了一种由化学式 1 表示的有机光电装置用化合物以及包括该化合物的有机光电装置。化学式 1 的结构已在说明书中描述。 该有机光电器件化合物用于形成有机光电器件的有机薄层，从而提供在低驱动电压下具有高发光效率和更长使用寿命的有机光电器件和显示器件。