(2-(bis[(ethyl-phenyl-carbamoyl)-methyl]-amino)-N-ethyl-N-phenyl-acetamide)tris(picrato)europium | 1011286-67-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2-(bis[(ethyl-phenyl-carbamoyl)-methyl]-amino)-N-ethyl-N-phenyl-acetamide)tris(picrato)europium
• CAS: 1011286-67-1
• 化学式: C₄₈H₄₂EuN₁₃O₂₄
• 分子量: 1336.89
• InChiKey: MUHQVZLVGWEGMO-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  europium(III) picrate 、 2-(bis[(ethyl-phenyl-carbamoyl)-methyl]-amino)-N-ethyl-N-phenyl-acetamide 以 乙醇 为溶剂， 以91%的产率得到(2-(bis[(ethyl-phenyl-carbamoyl)-methyl]-amino)-N-ethyl-N-phenyl-acetamide)tris(picrato)europium
  参考文献：
  名称：

  Self-organization of chiral self-complementary europium complex with a new achiral tripod-type ligand: Synthesis and stereochemistry effects to complex luminescence properties

  摘要：

  Solid complexes of europium picrate with the ligands: 2-(bis-dibutylcarbamoylmethyl-amino)-N,N-dibutyl-acetamid (L-1), 2-{bis-[(ethyl-phenyl-carbamoyl)-methyl]-amino}-N-ethyl-N-phenyl-acetamide (L-2) and 2-(bis-diethylcarbamoyl methyl-amino)-N,N-diethylacetamide (L-3) were prepared and characterized by elemental analysis, conductivity measurements and IR spectra. For the [Eu(pic)(3)L-1], X-ray measurements show that the screw coordination arrangement of the achiral tripod-type ligand (L-1) around the Eu(III) ion induces the chirality of clockwise (C) and anticlockwise (A) molecular structures. And, the luminescence properties of tripod-type ligands with Eu(III) ion were affected by the complex stereochemistry. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2007.03.008