4-(4'-methyl-2'-pyridyl)dibenzothiophene | 1051396-15-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻吩类
• 英文名称: 4-(4'-methyl-2'-pyridyl)dibenzothiophene
• 英文别名: 2-(4-Dibenzothienyl)-4-methylpyridine；2-dibenzothiophen-4-yl-4-methylpyridine
• CAS: 1051396-15-6
• 化学式: C₁₈H₁₃NS
• 分子量: 275.374
• InChiKey: ZSKRMGHVAHBIAJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  41.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  十二羰基三钌 、 4-(4'-methyl-2'-pyridyl)dibenzothiophene 以 甲苯 为溶剂， 以52%的产率得到[Ru(μ-(4-(4'-methyl-2'-pyridyl)dibenzothiophene(1-))-κ3N,C,S)(CO)2]2
  参考文献：
  名称：

  吡啶基取代的二苯并噻吩的C-S键裂解产生的钌和铑配合物与含硫酸酯的钳子配体

  摘要：

  4-（2'-吡啶基）二苯并噻吩的处理（PyDBT）与羰基钌簇的[Ru 3（CO）12 ]，得到二钌（II）配合物的[Ru（μ-PyBPT-κ 3 N，C，S）（ CO）2 ] 2（1），其中PyBPT表示3'-（2''-吡啶基）-1,1'-联苯-2-硫醇的二价阴离子。三齿-N，C，S PyBPT配体提供了一个由六元硫杂噻吩环和五元紫杉烷环组成的钳形结构。1中含有硫醇盐的NCS钳形配体通过裂解PyDBT中与吡啶基相邻的碳硫键产生。使用4-（4'-甲基-2'-吡啶基）二苯并噻吩（4-MePyDBT）和4-（6'-甲基-2'-吡啶基）二苯并噻吩（6-MePyDBT）的相应反应得到二钌（II）配合物用相同的钳框架的[Ru（μ-4- MePyBPT-κ 3 N，C，S）（CO）2 ] 2（2）和的[Ru（μ-6-MePyBPT-κ 3 N，C，S）（ CO）2 ] 2（3）。3的形成要慢得多通过吡啶

  DOI：

  10.1021/om8003916

文献信息

• [EN] ORGANIC ELECTROLUMINESCENT COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME<br/>[FR] COMPOSÉ ÉLECTROLUMINESCENT ORGANIQUE ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE COMPRENANT CE COMPOSÉ
  申请人：ROHM & HAAS ELECT MAT

  公开号：WO2016089162A1

  公开（公告）日：2016-06-09

  The present invention relates to a novel organic electroluminescent compound and an organic electroluminescent device comprising the same. By using the organic electroluminescent compound of the present invention, an organic electroluminescent device having excellent luminous properties can be produced.

  本发明涉及一种新型有机电致发光化合物和包括该化合物的有机电致发光器件。通过使用本发明的有机电致发光化合物，可以制备具有优异发光特性的有机电致发光器件。
• ORGANIC ELECTROLUMINESCENT COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME
  申请人：Rohm and Haas Electronic Materials Korea Ltd.

  公开号：US20170047528A1

  公开（公告）日：2017-02-16

  The present disclosure relates to an organic electroluminescent compound of Formula 1 (variables R1-R10 defined herein), and an organic electroluminescent device comprising the same. By using the organic electroluminescent compound according to the present disclosure, it is possible to produce an organic electroluminescent device which can be operated at a lowered driving voltage, shows excellence in luminous efficiency such as current efficiency and power efficiency, and has high color purity and improved lifespan.
• NOVEL ORGANIC ELECTROLUMINESCENT COMPOUNDS AND AN ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME
  申请人：Rohm and Haas Electronic Materials Korea Ltd.

  公开号：US20170305854A1

  公开（公告）日：2017-10-26

  The present disclosure relates to novel organic electroluminescent compounds and an organic electroluminescent device comprising the same. By using the organic electroluminescent compound of the present disclosure, the organic electroluminescent device may improve driving lifespan while maintaining equal or greater efficiency compared to conventional devices.
• [EN] ORGANIC ELECTROLUMINESCENT DEVICE<br/>[FR] DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE
  申请人：ROHM & HAAS ELECT MAT

  公开号：WO2016013875A1

  公开（公告）日：2016-01-28

  The present invention relates to an organic electroluminescent device. The organic electroluminescent device of the present invention shows high luminous efficiency and good lifespan by comprising a specific combination of the plural kinds of host compounds and a specific hole transport compound.