bis(3-thiophenecarboxaldehyde thiosemicarbazone)nickel(II) | 1161720-06-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: bis(3-thiophenecarboxaldehyde thiosemicarbazone)nickel(II)
• CAS: 1161720-06-4
• 化学式: C₁₂H₁₂N₆NiS₄
• 分子量: 427.221
• InChiKey: FMUSSKLXVJIPMH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  nickel(II) bromide trihydrate 、 thiophene-3-carboxaldehyde thiosemicarbazone 在 aq. NaOH 作用下， 以 乙醇 为溶剂， 生成 bis(3-thiophenecarboxaldehyde thiosemicarbazone)nickel(II)
  参考文献：
  名称：

  Synthesis, crystal structure and characterization of 3-thiophene aldehyde thiosemicarbazone and its complexes with cobalt(II), nickel(II) and copper(II)

  摘要：

  The reaction of cobalt(II), nickel(II), copper(II) chlorides and bromides with 3-thiophene aldehyde thiosemicarbazone (3TTSCH) leads to the formation of a series of new complexes: [Co(3TTSC)(2)], [Ni(3TTSC)(2)], [CuCl(3TTSC](2), [CuBr(3TTSC)](2) and [CuBr2 (3TTSCH)]. The crystal structures of the free ligand and of the compound [Ni(3TTSC)(2)] have been determined by X-ray diffraction methods. For all these complexes, the central ion is coordinated through the sulfur and the azomethine nitrogen atom of the thiosemicarbazone. [Co(3TTSC)(2)], [Ni(3TTSC)(2)] and [CuBr2(3TTSCH)] are mononuclear species, while [CuCl(3TTSC)](2) and [CuBr(3TTSC)](2) are binuclear complexes. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.02.042