spiro[dibenzo[c,h]xanthene-7,9′-fluorene] | 159-57-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡喃
• 英文名称: spiro[dibenzo[c,h]xanthene-7,9′-fluorene]
• 英文别名: spiro[dibenzo[c,h]xanthene-7,9'-fluorene]；Spiro(dibenzo[c,h]xanthen-7,9'-fluoren)；Spiro[2-oxapentacyclo[12.8.0.03,12.04,9.017,22]docosa-1(14),3(12),4,6,8,10,15,17,19,21-decaene-13,9'-fluorene]
• CAS: 159-57-9
• 化学式: C₃₃H₂₀O
• 分子量: 432.521
• InChiKey: YVZJIVUIVMAMNI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.8
• 重原子数：
  34
• 可旋转键数：
  0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  9-芴酮 、 萘酚 在 三氯氧磷 作用下， 生成 spiro[dibenzo[c,h]xanthene-7,9′-fluorene]
  参考文献：
  名称：

  Sen-Gupta, Journal of the Chemical Society, 1914, vol. 105, p. 401

  摘要：

  DOI：

文献信息

• ORGANIC ELECTROLUMINESCENT DEVICES COMPRISING BORANE COMPOUNDS
  申请人：Novaled GmbH

  公开号：EP3147958A1

  公开（公告）日：2017-03-29

  The present invention relates to an organic electroluminescent device comprising at least one semiconductive layer comprising a compound of formula (I) (I) wherein R1, R3 and R7 are independently selected from a group consisting of H, D, C1-C16 alkyl and C1-C16 alkoxy; R2, R4, R5 and R6 are independently selected from a group consisting of H, D, C1-C16 alkyl, C1-C16 alkoxy and C6-C20 aryl; Ar1 is selected from substituted or unsubstituted C6-C20 aryl, wherein, in case that Ar1 is substituted, the substituents are independently selected from a group consisting of D, C1-C12 alkyl, C1-C16 alkoxy and C6-C20 aryl; and Ar2 is selected from a group consisting of H, D, substituted or unsubstituted C6-C40 aryl and specific dibenzooxane and dibenzofuran derivaties.

  本发明涉及一种有机电致发光器件，该器件包含至少一个由式 (I) 化合物组成的半导体层 (I) 其中 R1、R3 和 R7 独立地选自由 H、D、C1-C16 烷基和 C1-C16 烷氧基组成的组； R2、R4、R5 和 R6 独立地选自由 H、D、C1-C16 烷基、C1-C16 烷氧基和 C6-C20 芳基组成的组； Ar1 选自取代或未取代的 C6-C20 芳基，其中，在 Ar1 被取代的情况下，取代基独立地选自 D、C1-C12 烷基、C1-C16 烷氧基和 C6-C20 芳基组成的组； Ar2 选自由 H、D、取代或未取代的 C6-C40 芳基和 特定的二苯并呋喃衍生物。
• ORGANIC SEMICONDUCTIVE LAYER COMPRISING PHOSPHINE OXIDE COMPOUNDS
  申请人：Novaled GmbH

  公开号：EP3171418A1

  公开（公告）日：2017-05-24

  The present invention relates to an organic semiconductive layer which is an electron transport layer and/or an electron injection layer and/or an n-type charge generation layer, the organic semiconductive layer comprising at least one compound of formula (1) wherein R1 and R2 are each independently selected from C1 to C16 alkyl; Ar1 is selected from C6 to C14 arylene or C3 to C12 heteroarylene; Ar2 is independently selected from C14 to C40 arylene or C8 to C40 heteroarylene; R3 is independently selected from H, C1 to C12 alkyl or C10 to C20 aryl; wherein each of Ar1, Ar2 and R3 may each independently be unsubstituted or substituted with at least one C1 to C12 alky group; n is 0 or 1; and m is 1 in case of n = 0; and m is 1 or 2 in case of n = 1, phosphine oxide compounds comprised therein and to organic electroluminescent devices comprising such layers and compounds.

  本发明涉及一种作为电子传输层和/或电子注入层和/或 n 型电荷发生层的有机半导体层，该有机半导体层包括至少一种式（1）化合物 其中 R1 和 R2 各自独立地选自 C1 至 C16 烷基；Ar1 选自 C6 至 C14 芳基或 C3 至 C12 杂芳基；Ar2 独立地选自 C14 至 C40 芳基或 C8 至 C40 杂芳基；R3 独立地选自 H、C1 至 C12 烷基或 C10 至 C20 芳基；其中 Ar1、Ar2 和 R3 可各自独立地未被取代或被至少一个 C1 至 C12 烷基取代；n 为 0 或 1；在 n = 0 的情况下，m 为 1；在 n = 1 的情况下，m 为 1 或 2。
• NOVEL COMPOUND AND ORGANIC LIGHT EMITTING DIODE COMPRISING SAME
  申请人：LG Chem, Ltd.

  公开号：EP3348552A1

  公开（公告）日：2018-07-18

  The present specification provides the compound represented by Chemical Formula 1 and an organic light emitting device including the same.

  本说明书提供了化学式 1 所代表的化合物以及包括该化合物的有机发光器件。
• Compound, material for organic electroluminescence devices, organic electroluminescence device, and electronic device
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US10424740B2

  公开（公告）日：2019-09-24

  A compound represented by formula (1) provides an organic electroluminescence device having a low driving voltage and an excellent emission efficiency: wherein R1 to R8, R11 to R18, R21 to R28, R31 to R38, X, Y, L1, L2, L3, and Ar are as defined in the description.

  式 (1) 所代表的化合物提供了一种具有低驱动电压和出色发射效率的有机电致发光器件： 其中 R1 至 R8、R11 至 R18、R21 至 R28、R31 至 R38、X、Y、L1、L2、L3 和 Ar 如说明中所定义。
• Compound and organic light emitting diode comprising same
  申请人：LG Chem, Ltd.

  公开号：US10686138B2

  公开（公告）日：2020-06-16

  The present specification provides the compound represented by Chemical Formula 1 and an organic light emitting device including the same.

  本说明书提供了化学式 1 所代表的化合物以及包括该化合物的有机发光器件。