5-(N-β-naphthalenesulfonyl)iminothianthrene | 947156-65-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 5-(N-β-naphthalenesulfonyl)iminothianthrene
• CAS: 947156-65-2
• 化学式: C₂₂H₁₅NO₂S₃
• 分子量: 421.565
• InChiKey: LBKCFMOYBUXMAX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.91
• 重原子数：
  28.0
• 可旋转键数：
  2.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  46.5
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  5-(N-β-naphthalenesulfonyl)iminothianthrene 在 二苯硫醚 作用下， 以 二氯甲烷 、 乙腈 为溶剂， 反应 1.0h， 生成 5-(N-p-Toluenesulfonyl)iminothianthrene
  参考文献：
  名称：

  Photo SN-bond cleavage and related reactions of thianthrene sulfilimine derivatives

  摘要：

  Several 1- and 2-substituted thianthrene sulfilimine derivatives were prepared and the selectivity toward oxidation and N-tosylimination under several conditions was studied. In the photolysis of trans-5-(N-p-tosyl) iminothianthrene 10-oxide (trans-10), photo isomerization to cis-10 was observed. Further, photoimino-transferreaction of sulfilimines and their 10-mono- and -dioxide derivatives to sulfides was intensively studied to make clear the ability as nitrene precursors. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2007.05.004
• 作为产物：
  描述：

  5-iminothianthrene 、 alkaline earth salt of/the/ methylsulfuric acid 在 三乙胺 作用下， 反应 1.0h， 以73%的产率得到5-(N-β-naphthalenesulfonyl)iminothianthrene
  参考文献：
  名称：

  Photo SN-bond cleavage and related reactions of thianthrene sulfilimine derivatives

  摘要：

  Several 1- and 2-substituted thianthrene sulfilimine derivatives were prepared and the selectivity toward oxidation and N-tosylimination under several conditions was studied. In the photolysis of trans-5-(N-p-tosyl) iminothianthrene 10-oxide (trans-10), photo isomerization to cis-10 was observed. Further, photoimino-transferreaction of sulfilimines and their 10-mono- and -dioxide derivatives to sulfides was intensively studied to make clear the ability as nitrene precursors. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2007.05.004