[Ph2(2,6-(t-BuOCH2)2C6H3)Sn(1-methylimidazole-2-thione)] | 928159-96-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: [Ph2(2,6-(t-BuOCH2)2C6H3)Sn(1-methylimidazole-2-thione)]
• CAS: 928159-96-0
• 化学式: C₃₂H₄₀N₂O₂SSn
• 分子量: 635.458
• InChiKey: VBKLWBHPXMCOPE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Ph2(2,6-(t-BuOCH2)2C6H3)Sn][OTf] 、 2-mercapto-1-methylimidazole sodium salt 以 四氢呋喃 为溶剂， 以59%的产率得到[Ph2(2,6-(t-BuOCH2)2C6H3)Sn(1-methylimidazole-2-thione)]
  参考文献：
  名称：

  Role of O,C,O-ligand in a new coordination mode of organotin compounds to 2-mercapto-1-methylimidazol. Stabilization of its thione form

  摘要：

  The reaction of the organotin compound [Ph2LSn](+) [OTf](-) (1), (L(O,C,O) = 2,6-(t-BuOCH2)(2)C6H3), with the sodium salt Na(mimt), mimt = 1-methylimidazole-2-thiolate, resulted in the isolation of Ph2LSn(mimt) (2), where the polar group (mimt) has been stabilized as the thione-tautomeric form by the triorganotin fragment Ph2LSn. Product 2 was characterized by H-1, C-13 and Sn-119 NMR and IR spectroscopy, ESI/MS, elemental analyses and X-ray diffraction. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.09.056