1,1,1-trichloro-3,3-difluoro-3-bromopropane | 690-36-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,1,1-trichloro-3,3-difluoro-3-bromopropane
• 英文别名: 1-bromo-3,3,3-trichloro-1,1-difluoro-propane；1,1,1-Trichlor-3-brom-3,3-difluor-propan；1-Brom-3,3,3-trichlor-1,1-difluor-propan
• CAS: 690-36-8
• 化学式: C₃H₂BrCl₃F₂
• 分子量: 262.309
• InChiKey: QZALYAWPIUDWLV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.73
• 重原子数：
  9.0
• 可旋转键数：
  1.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  1,1,1-trichloro-3,3-difluoro-3-bromopropane 在 三乙胺 作用下， 生成 1,1,1-Trichlor-3,3-difluor-propen-(2) 、 3-bromo-1,1-dichloro-3,3-difluoro-propene
  参考文献：
  名称：

  Notes- Synthesis of Some Haloolefins. Addition of Dibromodifluoromethane and Bromotrichloromethane to Vinylidene Fluoride

  摘要：

  DOI：

  10.1021/jo01079a602
• 作为产物：
  描述：

  三氯溴甲烷 、 偏氟乙烯 在 过氧化苯甲酰 作用下， 生成 1,1,1-trichloro-3,3-difluoro-3-bromopropane
  参考文献：
  名称：

  Notes- Synthesis of Some Haloolefins. Addition of Dibromodifluoromethane and Bromotrichloromethane to Vinylidene Fluoride

  摘要：

  DOI：

  10.1021/jo01079a602

文献信息

• Kinetics of radical telomerization of vinylidene fluoride in the presence of CCl3Z chain transfer agents
  作者：Michel Duc、Bruno Ameduri、Ghislain David、Bernard Boutevin

  DOI：10.1016/j.jfluchem.2006.11.004

  日期：2007.2

  The kinetics of radical telomerization of VDF at 141 degrees C, initiated by ditertbutylperoxide, in the presence of three chain transfer agents (CTAs), HCCl3, CCl4 and CCl3Br, are presented. The values of the chain transfer constants were assessed as 35, 0.25 and 0.06 at 141 degrees C for CCl3Br, CCl4 and HCCl3, respectively. The values of the degree of polymerization (DPn) were obtained for each CTA and were compared for the same CTA concentration. Hence, CCl3Br behaved as an efficient CTA towards VDF and usually afforded the monoadduct selectively, but in certain conditions the VDF diadduct can also be produced. In contrast, HCCl3 was not so efficient since a polymeric structure was identified as the major product. (c) 2006 Elsevier B.V. All rights reserved.