trans-diiodo-bis(5-isocyanoquinoline)palladium | 194281-87-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: trans-diiodo-bis(5-isocyanoquinoline)palladium
• CAS: 194281-87-3
• 化学式: C₂₀H₁₂I₂N₄Pd
• 分子量: 668.571
• InChiKey: PITCFPNHSMXYBD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  5-isocyanoquinoline 、 palladium(II) iodide 以 二氯甲烷 为溶剂， 以76%的产率得到trans-diiodo-bis(5-isocyanoquinoline)palladium
  参考文献：
  名称：

  Transition metal complexes of isocyanopyridines, isocyanoquinolines and isocyanoisoquinolines

  摘要：

  The complexes trans-[FeI2(CN-3-pyridyl)(4)], trans-[PdI2(CNR)(2)] (CNR = 2-, 3-and 4-isocyanopyridine, 3-isocyanoquinoline, 4-isocyanoquinaldine, 5-isocyanoquinoline, 5-isocyanoisoquinoline) and trans-[PtI2(CNR)(2)] (CNR = 3-isocyanopyridine, 5-isocyanoquinoline) were prepared. The new complexes are thermally stable up to 150 degrees C or higher. The molecular structure of trans-[PdI2(CN-3-quinolyl)(2)] was determined by X-ray crystallography: monoclinic space group P2(1)/c, a = 5.8381(5), b = 23.685(2), c = 7.2122(6) Angstrom, beta = 97.628(8)degrees, Z = 2, 1170 unique reflections, R = 0.035, R-w = 0.035. In the crystal, the molecular units are packed to form two-dimensional sheets which are held together by pi stacking of the 3-quinolyl groups.

  DOI：

  10.1016/s0020-1693(97)05459-5