N,N'-Bis--N,N'-diphenyl-benzidin | 87810-76-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N'-Bis--N,N'-diphenyl-benzidin
• 英文别名: 2-chloro-N-[4-[4-(N-(2-chlorophenyl)anilino)phenyl]phenyl]-N-phenylaniline
• CAS: 87810-76-2
• 化学式: C₃₆H₂₆Cl₂N₂
• 分子量: 557.522
• InChiKey: NGXPSFCDNMDGCI-UHFFFAOYSA-N

物化性质

• 沸点：
  684.2±55.0 °C(Predicted)
• 密度：
  1.264±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  11.3
• 重原子数：
  40
• 可旋转键数：
  7
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• PROCESS FOR PREPARING IODOAROMATIC COMPOUNDS AND USING THE SAME
  申请人：GOODBRAND Bruce H.

  公开号：US20050234272A1

  公开（公告）日：2005-10-20

  The present invention provides a process for preparing monoiodinated aromatic compounds that are useful as intermediates for preparing charge transporting and hole transporting amino compounds and have high purity with high yield and at low cost. A process for preparing aryl iodide compounds comprises reacting an aryl halide compound with a metal iodide, a metal catalyst and a catalyst coordinating ligand in at least one solvent to form an aryl iodide; and purifying the aryl iodide. A triarylamine compound and a process for preparing a triarylamine compounds reacting the aryl iodide with a diarylamine is also provided. Further, a photoconductive imaging member comprising a charge transport layer that comprises at least one triarylamine compound prepared reacting the aryl iodide with a diarylamine is provided.

  本发明提供了一种制备单碘芳香化合物的方法，这些化合物可用作制备传输电荷和传输空穴氨基化合物的中间体，并具有高纯度、高产率和低成本。制备芳基碘化合物的方法包括将芳基卤化物化合物与金属碘化物、金属催化剂和配体配位配体在至少一种溶剂中反应以形成芳基碘化合物；并纯化芳基碘化合物。还提供了一种三芳胺化合物和制备三芳胺化合物的方法，即将芳基碘化合物与二芳胺反应。此外，提供了一种包括至少一种通过将芳基碘化合物与二芳胺反应制备的三芳胺化合物的传输电荷层的光导成像成员。
• Organic dye compositions and use thereof in photovoltaic cells
  申请人：Zhang Ruzhou

  公开号：US20070028961A1

  公开（公告）日：2007-02-08

  The present invention provides in one aspect a composition having at least one croconine derivative. This composition may be disposed on a semiconductor layer which is further disposed on an electrically conductive surface to provide a dye-sensitized electrode. The dye-sensitized electrode can be assembled together with a counter electrode and a redox electrolyte to provide a photovoltaic cell. The photovoltaic cell may be used as a single cell or in tandem with other cells.

  本发明提供了一种具有至少一种紫红质衍生物的组合物。该组合物可以被置于半导体层上，该半导体层进一步置于导电表面上，以提供染料敏化电极。染料敏化电极可以与对电极和氧化还原电解质组装在一起，以提供光伏电池。光伏电池可以作为单个电池或与其他电池串联使用。
• Metal complex compositions and use thereof in dye sensitized solar cells
  申请人：Gui Yupeng John

  公开号：US20070017569A1

  公开（公告）日：2007-01-25

  The present invention provides in one aspect a composition having at least one metal complex, such that the metal complex comprises at least one metal atom, at least one first organic ligand comprising at least one triarylamine group, at least one second ligand comprising at least one acidic group, and at least one thiocyanate or isothiocyanate ligand. This composition may be disposed on a semiconductor layer which is further disposed on an electrically conductive surface to provide a dye-sensitized electrode. The dye-sensitized electrode can be assembled together with a counter electrode and a redox electrolyte to provide a dye-sensitized solar cell.

  本发明提供了一种组合物，其具有至少一个金属络合物，使得该金属络合物包含至少一个金属原子，至少一个第一有机配体，该配体包含至少一个三芳基胺基团，至少一个第二配体，该配体包含至少一个酸性基团，以及至少一个硫氰酸盐或异硫氰酸盐配体。该组合物可以被放置在半导体层上，该半导体层进一步放置在导电表面上，以提供染料敏化电极。染料敏化电极可以与对电极和氧化还原电解质一起组装，以提供染料敏化太阳电池。
• High mobility charge transporting molecules for a charge transport layer
  申请人：Xerox Corporation

  公开号：US20020076632A1

  公开（公告）日：2002-06-20

  Aryldiamine charge transporting molecules for a charge transport layer of an imaging member have a higher mobility by increasing the number of phenyl groups between the nitrogen atoms of the aryldiamine. The aryldiamine has the formula (X-Ph)(Y-Ph)-N-(Ph) n -N-(Ph-Y)(Ph-X), wherein Ph represents a phenyl group and in which (Ph) n consists of ortho- and/or para-conjugated unsubstituted phenyl groups, X represents a hydrogen atom or an alkyl group having from 1 to about 20 carbon atoms, Y represents a hydrogen atom or an alkyl group having from 1 to about 20 carbon atoms, and n is an integer greater than 3. A charge transport layer is prepared by molecularly dispersing or dissolving the aryldiamine charge transporting molecule in a polymeric binder.

  芳基二胺电荷传输分子可用于成像元件的电荷传输层，通过增加芳基二胺中氮原子之间苯基的数量，其具有更高的迁移率。 芳基二胺的化学式为（X-Ph）（Y-Ph）-N-（Ph）n-N-（Ph-Y）（Ph-X），其中Ph代表苯基，（Ph）n由邻位和/或对位共轭未取代的苯基组成，X代表氢原子或具有1至约20个碳原子的烷基，Y代表氢原子或具有1至约20个碳原子的烷基，n是大于3的整数。 通过将芳基二胺电荷传输分子分子分散或溶解在聚合物粘合剂中制备电荷传输层。
• Electrophotographic imaging member with improved charge generation layer
  申请人：XEROX CORPORATION

  公开号：EP0784234A2

  公开（公告）日：1997-07-16

  An electrophotographic imaging member comprising a support substrate having a two layered electrically conductive outer surface, a hole blocking layer, an adhesive layer comprising a copolyester resin, a charge generation layer comprising photoconductive perylene or phthalocyanine particles dispersed in a film forming resin binder blend comprising polyvinyl butryal copolymer and a copolyester selected from the group consisting of a first copolyester, a second copolyester and mixtures thereof, and a charge transport layer.

  一种电子照相成像部件，包括一个具有两层导电外表面的支撑基板、一个孔阻挡层、一个由共聚聚酯树脂组成的粘合层、一个电荷发生层，电荷发生层由分散在成膜树脂粘合剂混合物（包括聚乙烯醇丁二醛共聚物和选自第一共聚聚酯、第二共聚聚酯及其混合物组成的组的共聚聚酯）中的光导过烯烃或酞菁颗粒组成，以及一个电荷传输层。