tetraaminozinc(VI) peroxydisulfate | 39733-13-6

• 分子结构分类: 无机化合物
• 英文名称: tetraaminozinc(VI) peroxydisulfate
• CAS: 39733-13-6
• 化学式: H₁₂N₄Zn*O₈S₂
• 分子量: 325.639
• InChiKey: HAMZHYQDQXSKSV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ammonium hydroxide 、 zinc dioxide 、 ammonium peroxydisulfate 以0.21 g的产率得到tetraaminozinc(VI) peroxydisulfate
  参考文献：
  名称：

  四氨合过二硫酸锌(II)和过二硫酸钡四水合物的晶体结构

  摘要：

   抽象的 通过过二硫酸铵水溶液与锌相互作用合成了过二硫酸四氨锌[Zn(NH 3 ) 4 ]S 2 O 8 ( I )和四水过二硫酸钡BaS 2 O 8 ·4H 2 O ( II )分别是过氧化物和氢氧化钡。通过单晶X射线衍射确定晶体结构（CIF文件CCDC编号2311248（ I ）和2311249（ II ））。先前报道过 X 射线粉末衍射结构数据的I的晶体结构已被重新测定和澄清。 I的晶体堆积由平行于b轴的氢键链组成，这些链以三维结构连接，相邻链之间有氢键。化合物II是配位聚合物，钡阳离子的配位数等于9。II的晶体堆积由氢键固定水分子的通道组成。化合物I和II通过 DTA 和 TGA 进行表征，显示高达 170 和 90°C 的热稳定性。

  DOI：

  10.1134/s1070328423601553

文献信息

• Synthesis, vibrational spectra, and structure of divalent metal peroxodisulfates
  作者：L. S. Skogareva、N. A. Minaeva、T. V. Filippova

  DOI：10.1134/s0036023609090010

  日期：2009.9

  Simple strontium peroxodisulfate SrS2O8 center dot 4H(2)O was synthesized by the reaction of solid Sr(OH)(2) center dot 8H(2)O taken in 30% excess with an aqueous solution of (NH4)(2)S2O8; simple magnesium peroxodisulfate MgS2O8 center dot 6H(2)O was synthesized by the reaction of an aqueous solution of BaS2O8 with a stoichiometric amount of MgSO4 center dot 7H(2)O. Persulfate ammine complexes [M(NH3)(4)]S2O8 (M = Zn, Cu) were prepared in concentrated aqueous ammonia from [Zn(NH3)(4)](OH)(2), [Cu(NH3)(4)](OH)(2), and an ammoniac solution of (NH4)(2)S2O8. The compounds were characterized by X-ray powder diffraction (pRSA) and vibrational (IR and Raman) spectroscopy. Their stability was studied during storage and in DTA experiments. The [Zn(NH3)(4)]S2O8 structure was solved. Its crystals are orthorhombic, a = 10.5512(8) , b = 12.8039(12) , c = 8.0448(5) , V = 1086(15) (3), Z = 4, space group Pna2(1). The compound is built of [Zn(NH3)(4)](2+) complex cations and S2O (8) (2-) persulfate anions. In a cation, Zn-N bond lengths are within 2.04(2)-2.056(14) . In an anion, the lengths of S(1)-O(4), S(2)-O(5), and O(4)-O(5) bridging bonds are, respectively, 1.676(14), 1.672(16), and 1.465(16) ; the other S-O bond lengths are within 1.409(14)-1.443(12) ; the S(1)O(4)O(5)S(2) torsion angle is 140.8(7)A degrees.