(Z)-4-[(E)-Methylimino]-pent-2-en-2-ol | 130256-75-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (Z)-4-[(E)-Methylimino]-pent-2-en-2-ol
• CAS: 130256-75-6
• 化学式: C₆H₁₁NO
• 分子量: 113.159
• InChiKey: PYAOQKGLAPOAIK-XGXWUAJZSA-N

文献信息

• Metal-Organic Framework Catalysts and Their Use in Hydrocarbon Transformation
  申请人：Lillerud Karl-Petter

  公开号：US20080306315A1

  公开（公告）日：2008-12-11

  The invention relates to a porous heterogeneous catalyst material comprising frameworks of inorganic cornerstones connected by organic bridges, characterized in that as organic bridges are used ligands having a complexed catalytically active metal. The metals are preferably palladium and platinum. The ligands preferably contain nitrogen donor groups for complexing the catalytically active metal and carboxylate groups connecting to the inorganic cornerstones.

  这项发明涉及一种多孔的异质催化剂材料，其包括由无机基石通过有机桥连接而成的框架，其特征在于作为有机桥的配体是具有络合催化活性金属的。金属优选为钯和铂。配体优选包含氮供体基团以络合催化活性金属，并且连接到无机基石的羧基团。
• MASS POLYMERIZABLE POLYCYCLOOLEFIN COMPOSITIONS CONTAINING SOLUBLE PHOTOACID GENERATORS
  申请人：PROMERUS, LLC

  公开号：US20210380733A1

  公开（公告）日：2021-12-09

  Embodiments in accordance with the present invention encompass compositions comprising a soluble photoacid generator, a organopalladium compound, a photosensitizer and one or more olefinic monomers which undergo vinyl addition polymerization when said composition is exposed to a suitable actinic radiation to form a substantially transparent film. The monomers employed therein have a range of optical and mechanical properties, and thus these compositions can be tailored to form films having various opto-electronic properties. Accordingly, compositions of this invention are useful in various applications, including as coatings, encapsulants, fillers, leveling agents, among others.

  根据本发明的实施例，包括可溶性光酸发生剂、有机钯化合物、光敏剂和一种或多种烯烃单体的组合物被涵盖在内，当该组合物暴露于适当的光辐射下时，这些单体会经历乙烯基加成聚合反应，形成一个基本透明的薄膜。其中使用的单体具有不同的光学和机械性能，因此这些组合物可以定制成具有各种光电性能的薄膜。因此，本发明的组合物在各种应用中都是有用的，包括作为涂料、封装材料、填充剂、平整剂等。
• Use of a Combination Chain Transfer and Activating Agent to Control Molecular Weight and Optical Density of Pd Catalyzed Norbornene Polymers
  申请人：Rhodes Larry F.

  公开号：US20080242810A1

  公开（公告）日：2008-10-02

  A method of controlling the molecular weight of poly(cyclic) olefin (norbornene-type) polymers and activating the polymerization thereof with a single material is provided. Such method include adding a chain transfer/activating agent to a mixture of monomer(s), catalyst, solvent and an optional cocatalyst and polymerizing the mixture to form a polymer. It is shown that the amount of chain transfer/activating agent in the mixture can serve to control the molecular weight of the resulting polymer, its percent conversion or both, and in some embodiments the optical density of the resulting polymer.
• Use Of A Combination Chain Transfer And Activating Agent To Control Molecular Weight And Optical Density Of Pd Catalyzed Norbornene Polymers
  申请人：Rhodes Larry F.

  公开号：US20110009578A1

  公开（公告）日：2011-01-13

  A method of controlling the molecular weight of poly(cyclic) olefin (norbornene-type) polymers and activating the polymerization thereof with a single material is provided. Such method include adding a chain transfer/activating agent to a mixture of monomer(s), catalyst, solvent and an optional cocatalyst and polymerizing the mixture to form a polymer. It is shown that the amount of chain transfer/activating agent in the mixture can serve to control the molecular weight of the resulting polymer, its percent conversion or both, and in some embodiments the optical density of the resulting polymer.
• MICROWAVE-ASSISTED SYNTHESIS OF N-HETEROCYCLIC CARBENE TRANSITION METAL COMPLEXES
  申请人：Navarro Oscar

  公开号：US20130131343A1

  公开（公告）日：2013-05-23

  Microwave heating is used to synthesize NHC-transition metal complexes. Reaction times for the formation of NHC-transition metal complexes is greatly reduced. The speed of the reactions allows for otherwise problematic air handling of reagents. Apparatus for carrying out the reactions is less complex than conventional apparatus and requires less energy to achieve the desired temperatures. Methods utilize salts of NHC's which overcomes the oftentimes difficult preparation of free carbenes for formation of the corresponding transition metal complexes.