N1,N1'-([[1,1'-联苯]-4,4'-二基)双(N1-(4-甲氧基苯基)苯-1,4-二胺) | 1299494-47-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N1,N1'-([[1,1'-联苯]-4,4'-二基)双(N1-(4-甲氧基苯基)苯-1,4-二胺)
• 英文名称: N,N'-bis(4-aminophenyl)-N,N'-di(4-methoxylphenyl)-4,4'-biphenyldiamine
• 英文别名: N1,N1'-([1,1'-Biphenyl]-4,4'-diyl)bis(N1-(4-methoxyphenyl)benzene-1,4-diamine)；4-N-[4-[4-(4-amino-N-(4-methoxyphenyl)anilino)phenyl]phenyl]-4-N-(4-methoxyphenyl)benzene-1,4-diamine
• CAS: 1299494-47-5
• 化学式: C₃₈H₃₄N₄O₂
• 分子量: 578.714
• InChiKey: XQSXFRYYVKXVEF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  44
• 可旋转键数：
  9
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  77
• 氢给体数：
  2
• 氢受体数：
  6

安全信息

• 危险性防范说明：
  P261,P280,P301+P312,P302+P352,P305+P351+P338
• 危险性描述：
  H302,H315,H319,H335

反应信息

• 作为产物：
  描述：

  N,N'-Bis--N,N'-bis--benzidin 在 palladium 10% on activated carbon 、 一水合肼 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 反应 30.0h， 以84%的产率得到N1,N1'-([[1,1'-联苯]-4,4'-二基)双(N1-(4-甲氧基苯基)苯-1,4-二胺)
  参考文献：
  名称：

  Transmissive to black electrochromic aramids with high near-infrared and multicolor electrochromism based on electroactive tetraphenylbenzidine units

  摘要：

  利用新合成的芳香族二胺单体 N,N′-双（4-氨基苯基）-N,N′-二（4-甲氧基苯基）-4,4′-联苯二胺和各种二羧酸，通过磷酸化聚酰胺反应制备了一系列具有四苯基联苯胺（TPB）单元的近红外（NIR）电致发光芳香族聚酰胺。这些聚合物在许多有机溶剂中都有很高的溶解度，并显示出与高玻璃化转变温度和炭产量相关的热稳定性。这些阳极聚合物电致变色材料在可见光和近红外区域均表现出可逆的电化学和高对比度的电致变色特性。值得注意的是，TPB 基芳纶和 TPPA 基芳纶（TPPA：四苯基对苯二胺）的共聚显示出了单个均聚物在电化学和电致变色特性方面的良好结合，产生了一种具有高近红外和多色电致变色性能的透射到黑色的电致变色聚合物。

  DOI：

  10.1039/c1jm10210a

文献信息

• Electrochromic composition and electrochromic element
  申请人：INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE

  公开号：US10323122B2

  公开（公告）日：2019-06-18

  An electrochromic composition is provided. The electrochromic composition includes 0.5˜10 parts by weight of a first oxidizable polymer, 0.5˜10 parts by weight of a reducible organic compound, 0.5˜20 parts by weight of an electrolyte, and 60˜98.5 parts by weight of a solvent. The first oxidizable polymer is a polymer of 1 molar part of diamine and 0.1˜20 molar parts of dicarboxylic acid, diacyl chloride, or dianhydride, a mixture of the aforementioned polymers, or a copolymer of the aforementioned polymers. An electrochromic element including the aforementioned electrochromic composition is also provided.

  提供了一种电致变色组合物。电致变色组合物包括 0.5˜10（重量份）的第一可氧化聚合物、0.5˜10（重量份）的可还原有机化合物、0.5˜20（重量份）的电解质和 60˜98.5（重量份）的溶剂。第一种可氧化聚合物是由 1 摩尔份二元胺和 0.1 ˜20 摩尔份二羧酸、二酰氯或二酸酐组成的聚合物、上述聚合物的混合物或上述聚合物的共聚物。还提供了一种包括上述电致变色组合物的电致变色元件。
• Charge-transporting varnish and organic electro-luminescent devices made by using the same
  申请人：Ono Go

  公开号：US20070187672A1

  公开（公告）日：2007-08-16

  A charge-transporting varnish containing either a charge-transporting substance consisting of a charge-transporting oligoaniline or a charge-transporting organic material consisting of the charge-transporting substance and a charge-accepting dopant and at least one polymer selected from among polyimides and polyimide precursors; and charge-transporting thin films and organic EL devices, made by using the varnish. The varnish can give thin films which little suffer from defects and have high uniformity and flatness and excellent mechanical strengths, heat resistance, and transparency. In particular, the varnish realizes excellent EL characteristics such as low driving voltage, high emission efficiency, and long service life, when used in organic EL devices.
• TRANSPARENT ELECTROCHROMIC POLYMER AND ELECTROCHROMIC DEVICE
  申请人：INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE

  公开号：US20150241752A1

  公开（公告）日：2015-08-27

  A transparent electrochromic polymer is provided, which is polymerized of 1 molar part of a diamine and 1 to 4 molar parts of epoxy compound. The diamine is Formula 1, Formula 2, or combinations thereof, and the epoxy compound is Formula 12, Formula 13, or combinations thereof. The disclosed also provides an electrochromic device, including a first transparent conductive layer, an electrochromic layer on the first transparent conductive layer, and an electrolyte layer on the electrolyte layer, wherein the electrochromic layer is the transparent electrochromic polymer, and a second transparent conductive layer on the electrolyte layer.
• ELECTROCHROMIC COMPOSITION AND ELECTROCHROMIC ELEMENT
  申请人：INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE

  公开号：US20180186932A1

  公开（公告）日：2018-07-05

  An electrochromic composition is provided. The electrochromic composition includes 0.5˜10 parts by weight of a first oxidizable polymer, 0.5˜10 parts by weight of a reducible organic compound, 0.5˜20 parts by weight of an electrolyte, and 60˜98.5 parts by weight of a solvent. The first oxidizable polymer is a polymer of 1 molar part of diamine and 0.1˜20 molar parts of dicarboxylic acid, diacyl chloride, or dianhydride, a mixture of the aforementioned polymers, or a copolymer of the aforementioned polymers. An electrochromic element including the aforementioned electrochromic composition is also provided.
• US8822039B2
  申请人：——

  公开号：US8822039B2

  公开（公告）日：2014-09-02