N,N'-diphenyl-N,N'-bis[4'-(N-phenyl-N-3-methylphenylamino)-biphenyl-4-yl]benzidine | 169224-63-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N'-diphenyl-N,N'-bis[4'-(N-phenyl-N-3-methylphenylamino)-biphenyl-4-yl]benzidine
• 英文别名: 3-methyl-N-[4-[4-(N-[4-[4-(N-[4-[4-(N-(3-methylphenyl)anilino)phenyl]phenyl]anilino)phenyl]phenyl]anilino)phenyl]phenyl]-N-phenylaniline
• CAS: 169224-63-9
• 化学式: C₇₄H₅₈N₄
• 分子量: 1003.3
• InChiKey: PABSUVHIYYSWLB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  20.5
• 重原子数：
  78
• 可旋转键数：
  15
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  13
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• Organic EL element and compound used therein
  申请人：TDK Corporation

  公开号：EP0666298A2

  公开（公告）日：1995-08-09

  Tetraaryldiamine derivatives of formula (1) are used in organic EL elements. R1, R2, R3, and R4 represent aryl, alkyl, alkoxy, aryloxy, amino or halogen, at least one of R1 to R4 is an aryl group, r1, r2, r3, and r4 are 0 or an integer of 1 to 5, the sum of r1 to r4 is at least 1, R5 and R6 represent alkyl, alkoxy, amino or halogen, r5 and r6 are 0 or an integer of 1 to 4. The inventive compounds have high m.p. and high Tg and can be evaporated to deposit transparent smooth thin films of quality which maintain a stable amorphous state above room temperature over a long term. Organic EL elements using the inventive compounds in an organic compound layer, typically a hole injecting and transporting layer thereof provide uniform plane light emission and maintain a high intensity of luminescence in a stable manner over a long term. Thus the elements are fully durable and reliable.

  公式（1）的四芳基二胺衍生物被用于有机EL元件中。R1、R2、R3和R4代表芳基、烷基、烷氧基、芳氧基、氨基或卤素，其中至少一个是芳基基团，r1、r2、r3和r4为0或1至5的整数，r1到r4的总和至少为1，R5和R6代表烷基、烷氧基、氨基或卤素，r5和r6为0或1至4的整数。这些创新化合物具有高熔点和高Tg值，可以蒸发沉积成质量优良的透明平滑薄膜，在室温以上的长期稳定非晶态。在有机化合物层中使用这些创新化合物的有机EL元件，通常是其孔注入和传输层，提供均匀的平面光发射，并在长期稳定的情况下保持高亮度的荧光。因此，这些元件具有完全耐用和可靠的特点。
• ARYLAMINE COMPOUND AND ELECTROPHOTOGRAPHIC PHOTORECEPTOR
  申请人：WANG Yahui

  公开号：US20080153019A1

  公开（公告）日：2008-06-26

  An arylamine compound represented by formula (1): wherein R1 to R4 each independently represents a linear alkyl group or an arylalkenyl group, provided that when all of R1 to R4 represent linear alkyl groups, at least one of R1 to R4 represents a linear alkyl group having a carbon number of 3 or more; and an electrophotographic photoreceptor.

  一种芳胺化合物，其化学式表示为（1）：其中R1到R4各自独立地表示线性烷基或芳基烯基基团，但当R1到R4全部表示线性烷基时，至少有一个R1到R4表示具有3个或更多碳原子的线性烷基；以及一种电子照相光导体。
• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：TDK Corporation

  公开号：EP0857007A1

  公开（公告）日：1998-08-05

  In an organic EL device, a light emitting layer contains a specific coumarin derivative, and a hole injecting and/or transporting layer contains a specific tetraaryldiamine derivative. Also a light emitting layer in the form of a mix layer contains a specific coumarin derivative, a specific quinacridone compound or a specific styryl amine compound. There are provided at least two light emitting layers including a light emitting layer of the mix layer type wherein at least two dopants are contained so that at least two luminescent species may emit light. There is obtained an organic EL device capable of high luminance and continuous light emission and ensuring reliability. Multi-color light emission becomes possible.

  在有机电致发光器件中，发光层含有特定的香豆素衍生物，空穴注入和/或传输层含有特定的四芳基二胺衍生物。此外，混合层形式的发光层包含特定的香豆素衍生物、特定的喹吖啶酮化合物或特定的苯乙烯胺化合物。本发明提供了至少两个发光层，包括混合层类型的发光层，其中包含至少两种掺杂剂，从而至少有两种发光物质可以发光。这样就得到了一种有机 EL 器件，它能够实现高亮度和连续发光，并确保可靠性。多色发光成为可能。
• Organic EL device
  申请人：TDK CORPORATION

  公开号：US20020038867A1

  公开（公告）日：2002-04-04

  In an organic EL device, a light emitting layer contains a specific coumarin derivative, and a hole injecting and/or transporting layer contains a specific tetraaryldiamine derivative. Also a light emitting layer in the form of a mix layer contains a specific coumarin derivative, a specific quinacridone compound or a specific styryl amine compound. There are provided at least two light emitting layers including a light emitting layer of the mix layer type wherein at least two dopants are contained so that at least two luminescent species may emit light. There is obtained an organic EL device capable of high luminance and continuous light emission and ensuring reliability. Multi-color light emission becomes possible.

  在有机电致发光器件中，发光层含有特定的香豆素衍生物，空穴注入和/或传输层含有特定的四芳基二胺衍生物。此外，混合层形式的发光层包含特定的香豆素衍生物、特定的喹吖啶酮化合物或特定的苯乙烯胺化合物。本发明提供了至少两个发光层，包括混合层类型的发光层，其中包含至少两种掺杂剂，从而至少有两种发光物质可以发光。这样就得到了一种有机 EL 器件，它能够实现高亮度和连续发光，并确保可靠性。多色发光成为可能。
• Organic EL Device
  申请人：TDK Corporation

  公开号：EP1342769B1

  公开（公告）日：2010-01-27