4-<2-(4-fluorophenyl)ethyl>phenol | 137372-64-6

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 4-<2-(4-fluorophenyl)ethyl>phenol
• 英文别名: 4-[2-(4-Fluorophenyl)ethyl]phenol
• CAS: 137372-64-6
• 化学式: C₁₄H₁₃FO
• 分子量: 216.255
• InChiKey: IZBWYSKGMBPNDW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  (E)-4-<2-(4-fluorophenyl)ethenyl>phenol 在 palladium on activated charcoal 氢气 作用下， 以86%的产率得到4-<2-(4-fluorophenyl)ethyl>phenol
  参考文献：
  名称：

  Comparison of the fungicidal activities of (E)-4-hydroxylated stilbenes and related bibenzyls

  摘要：

  The fungicidal activities of (E)-4-hydroxylated stilbenes and related bibenzyls were measured by the agar plate procedure and selected active compounds by the soil block method. In the agar plate test, stilbenes with 3'-substituents were all active against two brown-rot (G. trabeum and P. placenta) fungi, with the activity having a parabolic hydrophobic relationship. A highly fungitoxic monomer was used to synthesize a dehydrogenative dimer which showed no brown-rot activity. No stilbene was active against the white-rot fungi C. versicolor while three bibenzyls had white-rot activity. Most bibenzyls had moderate brown-rot fungicidal activity. No structural requirement was apparent for bibenzyl brown-rot activity in contrast to the stilbenes. No synergism was observed when various combinations of stilbenes and bibenzyls were tested by the agar plate procedure. Similarities were observed between the agar plate activity and soil block results, although the soil block required higher levels of the stilbene/bibenzyl. No synergism was observed in the soil block results for stilbene and/or bibenzyl combinations. Stilbenes and/or bibenzyls in combination with didecyldimethylammonium chloride, however, showed some synergism.

  DOI：

  10.1016/s0031-9422(00)98228-1

文献信息

• Fluorinated aromatic polymer and use thereof
  申请人：ASAHI GLASS COMPANY LIMITED

  公开号：US20040147710A1

  公开（公告）日：2004-07-29

  To provide a fluorinated aromatic polymer having excellent heat resistance and a low relative permittivity; and an insulating film for electronic devices and an insulating film for multilayered wiring boards, which are made of the polymer. A fluorinated aromatic polymer which contains two or more crosslinkable functional groups (A) per molecule and has a number average molecular weight of from 1×10 3 to 5×10 5 and an ether linkage and which is produced by e.g. a method in which a branched fluorinated aromatic compound (B) represented by the formula 1 and a compound (Y1) having a crosslinkable functional group (A) and a phenolic hydroxyl group, are subjected to a condensation reaction in the presence of a HF-removing agent: 1

  提供一种具有优异耐热性和低相对介电常数的含氟芳香族聚合物，以及由该聚合物制成的电子设备绝缘膜和多层布线板绝缘膜。一种氟化芳香族聚合物，其每个分子含有两个或两个以上的可交联官能团（A），其平均分子量为 1×10 3 至 5×10 5 的支链氟化芳香族化合物(B)和具有可交联官能团(A)和酚羟基的化合物(Y1)，在氢氟酸脱除剂存在下进行缩合反应： 1
• US6881811B2
  申请人：——

  公开号：US6881811B2

  公开（公告）日：2005-04-19
• Comparison of the fungicidal activities of (E)-4-hydroxylated stilbenes and related bibenzyls
  作者：T.P. Schultz、Q. Cheng、W.D. Boldin、T.F. Hubbard、L. Jin、T.H. Fisher、D.D. Nicholas

  DOI：10.1016/s0031-9422(00)98228-1

  日期：1991.1

  The fungicidal activities of (E)-4-hydroxylated stilbenes and related bibenzyls were measured by the agar plate procedure and selected active compounds by the soil block method. In the agar plate test, stilbenes with 3'-substituents were all active against two brown-rot (G. trabeum and P. placenta) fungi, with the activity having a parabolic hydrophobic relationship. A highly fungitoxic monomer was used to synthesize a dehydrogenative dimer which showed no brown-rot activity. No stilbene was active against the white-rot fungi C. versicolor while three bibenzyls had white-rot activity. Most bibenzyls had moderate brown-rot fungicidal activity. No structural requirement was apparent for bibenzyl brown-rot activity in contrast to the stilbenes. No synergism was observed when various combinations of stilbenes and bibenzyls were tested by the agar plate procedure. Similarities were observed between the agar plate activity and soil block results, although the soil block required higher levels of the stilbene/bibenzyl. No synergism was observed in the soil block results for stilbene and/or bibenzyl combinations. Stilbenes and/or bibenzyls in combination with didecyldimethylammonium chloride, however, showed some synergism.