tris(1,10-phenanthroline)ruthenium(II) sulfate | 89554-09-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: tris(1,10-phenanthroline)ruthenium(II) sulfate
• CAS: 89554-09-6；41745-79-3
• 化学式: C₃₆H₂₄N₆Ru*O₄S
• 分子量: 737.76
• InChiKey: KXTCZQQCTNSPNA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  tris(1,10-phenanthroline)ruthenium(II) sulfate 在 lead dioxide 作用下， 以 硫酸 为溶剂， 生成 [Ru(III)(1,10-phenanthroline)3]sulfato
  参考文献：
  名称：

  [Ru(phen)3]2+ 催化的溴丙二酸/溴酸盐体系中的振荡

  摘要：

  We investigated the oscillatory behavior of a BZ system with bromomalonic acid and bromate as substrates and with [Ru(phen)(3)] SO4 as a catalyst. The observed oscillations can be well modeled with a theory based on two different feedback loops originally developed for a corresponding BZ system with [Ru(bipy)(3)] SO4 as a catalyst. Furthermore, we have reexamined the decomposition of acidic bromate. We conclude that the products of this reaction are HOBr and O-2 rather than HOBr and perbromate; the rate constant for the decomposition reaction turns out to be 1000 times smaller for 1 M sulfuric acid solution than expected from earlier experiments performed with 3 M sulfuric acid solutions.

  DOI：

  10.1021/jp992128c
• 作为产物：
  描述：

  tris(1,10-phenanthroline)ruthenium(II) dichloride 、 硫酸 以 水 为溶剂， 生成 tris(1,10-phenanthroline)ruthenium(II) sulfate
  参考文献：
  名称：

  [Ru(phen)3]2+ 催化的溴丙二酸/溴酸盐体系中的振荡

  摘要：

  We investigated the oscillatory behavior of a BZ system with bromomalonic acid and bromate as substrates and with [Ru(phen)(3)] SO4 as a catalyst. The observed oscillations can be well modeled with a theory based on two different feedback loops originally developed for a corresponding BZ system with [Ru(bipy)(3)] SO4 as a catalyst. Furthermore, we have reexamined the decomposition of acidic bromate. We conclude that the products of this reaction are HOBr and O-2 rather than HOBr and perbromate; the rate constant for the decomposition reaction turns out to be 1000 times smaller for 1 M sulfuric acid solution than expected from earlier experiments performed with 3 M sulfuric acid solutions.

  DOI：

  10.1021/jp992128c

文献信息

• Proton Chemical Shift Study of the Hydrophobic Interaction between Tris(1,10-phenanthroline)ruthenium(II) Ions in Aqueous Solutions
  作者：Yuichi Masuda、Hideo Yamatera

  DOI：10.1246/bcsj.57.58

  日期：1984.1

  that the up-field shifts were caused by the interaction between[Ru(phen)3]2+ ions. Assuming the formation of the triple and quadrupole aggregates containing two [Ru(phen)3]2+ ions, the association constants of these aggregates and the up-field shifts of the proton signals in the aggregates were determined. A probable structure of the aggregates was deduced from the measured chemical shifts by attributing

  在[Ru(phen)3]SO4 的D2O 溶液中测量质子NMR 化学位移。随着[Ru(phen)3]SO4 浓度的增加，菲咯啉配体的质子共振显示场上移，但它们不受添加Na2SO4 的显着影响。Λ-[Ru(phen)3]SO4 溶液的上场位移曲线与 rac-[Ru(phen)3]SO4 溶液的不同。这些结果证明上场位移是由[Ru(phen)3]2+ 离子之间的相互作用引起的。假设形成了包含两个 [Ru(phen)3]2+ 离子的三重和四极聚集体，这些聚集体的缔合常数和聚集体中质子信号的向上场位移被确定。通过将聚集体中的上场位移归因于菲咯啉配体的环流效应，从测量的化学位移中推断出聚集体的可能结构。[Ru(phen)3]2+ 离子在水溶液中疏水相互作用的重要性...