申请人:Leclerc Margarete K.
公开号:US20100048841A1
公开(公告)日:2010-02-25
Ligands, compositions, and metal-ligand complexes that incorporate phenol-heterocyclic compounds are disclosed that are useful in the catalysis of transformations such as the polymerization of monomers into polymers. The catalysts have high performance characteristics, including high comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts particularly polymerize styrene to form polystyrene.
本发明揭示了包含酚-杂环化合物的配体、组合物和金属配合物,这些配体、组合物和金属配合物在催化转化中非常有用,例如将单体聚合成聚合物。催化剂具有高性能特征,包括将共聚单体高度并入乙烯/烯烃共聚物中,其中所述烯烃例如为1-辛烯、丙烯或苯乙烯。该催化剂特别是将苯乙烯聚合成聚苯乙烯。