[Mn(N,N'-(1,1,2,2-tetramethylethylene)bis(naphthylideneiminato)(H2O)]ClO4 | 178969-51-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [Mn(N,N'-(1,1,2,2-tetramethylethylene)bis(naphthylideneiminato)(H2O)]ClO4
• 英文别名: [Mn(naphtmen)(H2O)]ClO4
• CAS: 178969-51-2
• 化学式: C₂₈H₂₈MnN₂O₃*ClO₄
• 分子量: 594.931
• InChiKey: OUSBGGLUHKSVED-GYCDCWHSSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  TETRABUTYLAMMONIUM HEXACYANOFERRATE(III) 、 [Mn(N,N'-(1,1,2,2-tetramethylethylene)bis(naphthylideneiminato)(H2O)]ClO4 以 甲醇 、 异丙醇 为溶剂， 反应 2.0h， 生成 [{Mn(N,N′-(1,1,2,2-tetramethylethylene)bis(naphthylideneiminato))}₄{Fe(CN)₆}]ClO₄
  参考文献：
  名称：

  源自锰 (III) 席夫碱和六氰基铁酸盐 (III) 结构单元的三核和五核配合物

  摘要：

  基于锰（III）席夫碱和六氰基铁酸盐（III）单元的三核和五核氰基桥连络合物，即[{Mn(naphtmen)}2{Fe(CN)6}][Mn(naphtmen)(CH3OH) )2]2ClO4·5CH3OH·H2O [1; naphtmen2– = N,N'-(1,1,2,2-四甲基亚乙基)bis(naphthylideneiminato) dianion] 和 [{Mn(naphtmen)}4{Fe(CN)6}]ClO4 (2)，合成并通过 X 射线单晶衍射进行结构表征。结构分析表明，1 由 [{Mn(naphtmen)}2{Fe(CN)6}]– 阴离子的线性三核簇组成，它们通过平面外的双酚桥进一步连接成一维链。在2中，获得了磁性分离的氰基桥连五核{[Mn(naphtmen)]4[Fe(CN)6]}+阳离子。温度相关的磁化率表明 FeIII 和 MnIII 离子之间通过氰基桥的交换相互作用在

  DOI：

  10.1002/ejic.201600339
• 作为产物：
  描述：

  N,N'-(1,1,2,2-tetramethylethylene)bis(3-hydroxy-4-naphthylideneiminate) 、 sodium perchlorate 、 manganese(III) triacetate dihydrate 以 甲醇 、 水 为溶剂， 生成 [Mn(N,N'-(1,1,2,2-tetramethylethylene)bis(naphthylideneiminato)(H2O)]ClO4
  参考文献：
  名称：

  Bimetallic Materials Derived from Manganese(III) Schiff Base Complexes and Pentacyanidonitrosylferrate(II) Precursor: Structures and Magnetic Properties

  摘要：

  Three complexes, [Mn(salphen)(H2O)(12)[Fe(CN)(5)(NO)]center dot 2CH(3)OH (1) (salphen = N,N'-phenylenebis(salicylide-neiminato) dianion), [Mn(naphtmen)(CH3OH)(12)[Fe(CN)(5)(NO)] (2) (naphtmen = N,N'-(1,1,2,2-tetramethylethylene)-bis(naphthylideneiminato) dianion), and {[Mn(salen)](2)[Fe(CN)(5)(NO)]center dot H2O}(n) (3) (salen = N,N'-ethylene-bis-(salicylideneiminato) dianion), were synthesized and structurally characterized by X-ray single-crystal diffraction. The structural analyses show that complexes 1 and 2 consist of the discrete linear trinuclear [Mn(SB)](2)[Fe(CN)(5)(NO)] units (SB = salphen for 1, naphtmen for 2); in complex 3, the nitroprusside anion coordinates to the axial sites of the four [Mn(salen)](+) entities through its four cyano nitrogen atoms, providing a two-dimensional network. The magnetic analysis indicates that the nitroprusside bridging ligand propagates a very weak antiferromagnetic exchange and single-ion anisotropy (D) plays an important role in the overall magnetic properties. Different from complexes 2 and 3, complex 1 shows a typical spin-flop transition with a critical field of 20 kOe.

  DOI：

  10.1021/ic901600v