[Mn(N,N'-phenylenebis(salicylideneiminato)(H2O)]ClO4 | 1207615-05-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: [Mn(N,N'-phenylenebis(salicylideneiminato)(H2O)]ClO4
• 英文别名: [Mn(salphen)(H2O)]ClO4
• CAS: 1207615-05-1；852529-30-7
• 化学式: C₂₀H₁₆MnN₂O₃*ClO₄
• 分子量: 486.747
• InChiKey: ARJKBQPFEYUNBM-MYHDMYFSSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  乙腈 、 tetra-butylammonium bis(1,2-benzenedithiolate)nickel 、 [Mn(N,N'-phenylenebis(salicylideneiminato)(H2O)]ClO4 以 乙腈 为溶剂， 生成 [Mn2(N,N'-o-phenylenebis(salicylideneaminato))2(μ-OH)][Ni(1,2-benzenedithiolate)2](CH3CN)2
  参考文献：
  名称：

  Ferromagnetic interaction between [Ni(bdt)2]− anions in [Mn2(Saloph)2(μ-OH)][Ni(bdt)2](CH3CN)2

  摘要：

  A new molecule-based magnetic material [Mn-2(Saloph)(2)(mu-OH)][Ni(bdt)(2)](CH3CN)(2) was prepared by the metathesis of [Mn(Saloph)(H2O)(ClO4)] (S = 2) and TBA[Ni(bdt)(2)] (S = 1/2). In the crystal, [Ni(bdt)(2)](-) anions form square lattices which are separated from each other by the layers of antiferromagnetically coupled binuclear cations [Mn-2(Saloph)(2)(mu-OH)](+). The magnetic susceptibility of the material coincides with the sum of the S = 2 van Vleck dimer model and S = 1/2 Heisenberg ferromagnetic square lattice model with 2J = -92.4 and +4.5 K, respectively. The origin of the ferromagnetic interaction can be explained by the T-shaped intermolecular overlap mode of SOMOs which spreads to the ends of [Ni(bdt)(2)](-) molecules. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.10.022
• 作为产物：
  描述：

  N,N'-二水杨醛缩-1,2-苯二胺 、 manganese(II) perchlorate hexahydrate 在 N(CH₂CH₃)3 作用下， 以 乙腈 为溶剂， 生成 [Mn(N,N'-phenylenebis(salicylideneiminato)(H2O)]ClO4
  参考文献：
  名称：

  的合成和一些锰（II）表征和Mn（III）络合物Ñ，Ñ ' - Ö -phenylenebis（salicylideneimine）（LH 2）和Ñ，Ñ ' - Ö -phenylenebis（5- bromosalicylideneimine）（L'ħ 2）。[Mn（L）（H 2 O）（ClO 4）]，[Mn（L）（NCS）]的晶体结构和[Mn（L）（OAc）]的无限线性链

  摘要：

  合成了一系列锰（II）[Mn（L）]和锰（III）[Mn（L）（X）]（X = ClO 4，OAc，NCS，N 3，Cl，Br和I）配合物从席夫碱配体ñ，ñ ' - ö -phenylenebis（salicylideneimine）（LH 2）和ñ，ñ ' - ö -phenylenebis（5- bromosalicylideneimine）（L'ħ 2由水杨醛或5 -溴水杨醛缩合得到）邻苯二胺。通过红外光谱，紫外可见光谱，磁测量和电化学研究相结合，对复合物进行了表征。三种锰（III）配合物3 [Mn（L）（ClOX射线晶体学表征了4）（H 2 O），5 [Mn（L）（OAc）]和13 [Mn（L）（NCS）]。X射线结构表明，锰（III）在3中是六配位的，在13中是五配位的，而在5中存在无限的链，其中MnL部分通过充当桥联二齿配体的乙酸根离子连接。所有锰（III）配合物的循环伏安图均

  DOI：

  10.1016/j.ica.2005.01.026

文献信息

• Azide-Bridged One-Dimensional Mn^III Polymers:  Effects of Side Group of Schiff Base Ligands on Structure and Magnetism
  作者：Mei Yuan、Fei Zhao、Wen Zhang、Zhe-Ming Wang、Song Gao

  DOI：10.1021/ic701655w

  日期：2007.12.1

  By changing ancillary tetradentate Schiff base ligands (L), two new one-dimensional azide-bridged manganese(III) coordination complexes [MnIII(L)(mu1,3-N3)]n [L = 5-Fsalen (1), 5-OCH3 (2); salen = N,N'-bis(salicylidene)-1,2-diaminoethane] as well as a mononuclear complex [MnIII(salophen)(N3)] (3) [salophen = N,N'-bis(salicylidene)-o-phenylenediamine] have been successfully obtained. All of them have

  通过更改辅助四齿席夫碱配体（L），形成两个新的一维叠氮桥联锰（III）配位化合物[MnIII（L）（mu1,3-N3）] n [L = 5-Fsalen（1），5 -OCH 3（2）；salen = N，N'-双（水杨基亚基）-1,2-二氨基乙烷]以及单核络合物[MnIII（salophen）（N3）]（3）[salophen = N，N'-双（水杨基）-o -苯二胺]已成功获得。所有这些都已在结构和磁性上进行了表征。在1-3的结构中，每个MnIII离子呈扭曲的八面体几何形状，具有明显的Jahn-Teller效应，其中四齿L配体全部以赤道模式结合，而在轴向N3离子作为末端-在1和2中形成末端桥，而在3中的末端基团的另一端带有甲醇分子。磁特性表明，mu1，事实证明，三桥叠氮化物离子主要在MnIII离子之间传递反铁磁相互作用，但是这三种络合物在低温下表现出各种磁行为。值得注意的是，复合物2表现为弱的铁磁体，具有2
• Bimetallic Materials Derived from Manganese(III) Schiff Base Complexes and Pentacyanidonitrosylferrate(II) Precursor: Structures and Magnetic Properties
  作者：Chun Yang、Qing-Lun Wang、Yue Ma、Guo-Tao Tang、Dai-Zheng Liao、Shi-Ping Yan、Guang-Ming Yang、Peng Cheng

  DOI：10.1021/ic901600v

  日期：2010.3.1

  Three complexes, [Mn(salphen)(H2O)(12)[Fe(CN)(5)(NO)]center dot 2CH(3)OH (1) (salphen = N,N'-phenylenebis(salicylide-neiminato) dianion), [Mn(naphtmen)(CH3OH)(12)[Fe(CN)(5)(NO)] (2) (naphtmen = N,N'-(1,1,2,2-tetramethylethylene)-bis(naphthylideneiminato) dianion), and [Mn(salen)](2)[Fe(CN)(5)(NO)]center dot H2O}(n) (3) (salen = N,N'-ethylene-bis-(salicylideneiminato) dianion), were synthesized and structurally characterized by X-ray single-crystal diffraction. The structural analyses show that complexes 1 and 2 consist of the discrete linear trinuclear [Mn(SB)](2)[Fe(CN)(5)(NO)] units (SB = salphen for 1, naphtmen for 2); in complex 3, the nitroprusside anion coordinates to the axial sites of the four [Mn(salen)](+) entities through its four cyano nitrogen atoms, providing a two-dimensional network. The magnetic analysis indicates that the nitroprusside bridging ligand propagates a very weak antiferromagnetic exchange and single-ion anisotropy (D) plays an important role in the overall magnetic properties. Different from complexes 2 and 3, complex 1 shows a typical spin-flop transition with a critical field of 20 kOe.