(Bicyclo[2.2.1]hept-2-ene-1,2-diyl)dimethanamine | 57323-66-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (Bicyclo[2.2.1]hept-2-ene-1,2-diyl)dimethanamine
• 英文别名: [1-(aminomethyl)-2-bicyclo[2.2.1]hept-2-enyl]methanamine
• CAS: 57323-66-7
• 化学式: C₉H₁₆N₂
• 分子量: 152.24
• InChiKey: QVCYAGDLZWFGEC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.5
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

文献信息

• METHOD OF PREPARING DIISOCYANATE COMPOSITION
  申请人：SKC CO., LTD.

  公开号：US20210171449A1

  公开（公告）日：2021-06-10

  In the embodiments, an aqueous hydrochloric acid solution instead of hydrogen chloride gas and solid triphosgene instead of phosgene gas may be used in the process of preparing a diisocyanate from a diamine through a diamine hydrochloride. In addition, the embodiments provide processes for preparing a diisocyanate composition and an optical lens, which are excellent in yield and quality with mitigated environmental problems by controlling the size of the diamine hydrochloride composition, the b* value according to the CIE color coordinate of the diamine hydrochloride composition, or the content of water in the diamine hydrochloride composition within a specific range.

  在实施例中，制备二异氰酸酯的过程中，可以使用水溶性盐酸溶液代替氢氯酸气体，以及使用固态三噁烯代替光气气体。此外，实施例提供了制备二异氰酸酯组合物和光学透镜的方法，通过控制盐酸二胺组成物的尺寸、CIE颜色坐标中的b*值或盐酸二胺组成物中水的含量在特定范围内，获得高产率和高质量的同时减少环境问题。
• PROCESS FOR THE PRODUCTION OF ALIPHATIC ISOCYANATES
  申请人：Daussin Rory D.

  公开号：US20110275854A1

  公开（公告）日：2011-11-10

  The present invention is a process for aliphatic or cycloaliphatic isocyanate. The process comprises reacting an aliphatic or cycloaliphatic primary amine, with phosgene in the presence of an inert solvent wherein the initial reaction temperature is between 100 and 130° C. and the temperature is subsequently ramped to 150 to 180° C. during the course of the reaction, the solvent to amine weight ratio is 95:5 to 80:20, the total reaction pressure is maintained between 50 and 350 psig and the amine is rapidly dispersed in the phosgene through injection in a region of high efficiency mixing.

  本发明是一种制备脂肪族或环脂肪族异氰酸酯的方法。该方法包括在惰性溶剂存在下，将脂肪族或环脂肪族初级胺与光气反应，其中初始反应温度在100至130℃之间，反应过程中逐渐升温至150至180℃，溶剂与胺的重量比为95:5至80:20，总反应压力保持在50至350 psig之间，并且通过在高效混合区注入使胺迅速分散在光气中。
• Norbornyl modified polyesteramides and process for preparing same
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0134263A1

  公开（公告）日：1985-03-20

  Polyesteramides modified by having at least one terminal norbornene radical have improved physical and chemical properties, such as enhanced corrosion resistance, electrical properties, and heat stability. The modified polyesteramides are prepared by a process of reacting a dicarboxylic acid, a diamine, a polyol and a norbomene compound.

  通过至少一个末端降冰片烯基改性的聚酯酰胺具有更好的物理和化学性质，如更强的耐腐蚀性、电性能和热稳定性。改性聚酯酰胺是通过二羧酸、二胺、多元醇和降冰片烯化合物的反应过程制备的。
• Polyesteramide concrete
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0149028A2

  公开（公告）日：1985-07-24

  Polymer concrete compositions are made from norbornyl modified unsaturated polyesteramide compositions. The curable concrete composition contains 2 to 20 percent by weight of the polyesteramide composition and 98 to 80 percent by weight of an aggregate such as sand, gravel, silica flour, etc. The polyesteramide composition contains norbornyl modified polyesteramide, ethylenically unsaturated monomers, such as styrene with or without a vinyl reactive additive. The polyesteramide can be further modified to' contain a copolymerized polyether polyol having a function- arty of three or more, a copolymerized poly(2-alkyl-2-oxazoline) or a copolymerized carboxylated rubber. The vinyl reactive additive can be a vinyl ester resin or a vinyl terminated urethane oligomer: When cured, the curable concrete composition gives a polymer concrete with better tensile and compressive strength with the advantage that the composition cures under water and in the presence of moisture.

  聚合物混凝土组合物由降冰片烷基改性的不饱和聚酯酰胺组合物制成。可固化混凝土组合物含有 2%至 20%（按重量计）的聚酯酰胺组合物和 98%至 80%（按重量计）的骨料，如砂、砾石、硅粉等。聚酯酰胺组合物含有降冰片烷基改性聚酯酰胺、乙烯基不饱和单体，如苯乙烯，可添加或不添加乙烯基反应添加剂。聚酯酰胺还可进一步改性为含有官能度为 3 或 3 以上的共聚聚醚多元醇、共聚聚（2-烷基-2-噁唑啉）或共聚羧基橡胶。乙烯基活性添加剂可以是乙烯基酯树脂或乙烯基端聚氨酯低聚物：固化后的混凝土组合物具有更好的抗拉强度和抗压强度，同时还具有在水中和潮湿环境下固化的优点。
• COMPOSITION FOR OPTICAL MATERIAL
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：EP1426392A1

  公开（公告）日：2004-06-09

  The composition for optical materials of the present invention comprises a compound having in one molecule at least one structure represented by the following formula (1): wherein R1, R2, R3, R4, X, Y and n are as defined in the disclosure, an amine compound and an isocyanate compound. Resins obtained by curing the composition by polymerization are useful as well-balanced optical materials having a high impact resistance, a high refractive index and a sufficiently high Abbe's number.

  本发明的光学材料组合物包括在一个分子中至少具有下式（1）所代表的一种结构的化合物： 其中 R1、R2、R3、R4、X、Y 和 n 如公开资料中所定义；胺化合物和异氰酸酯化合物。通过聚合固化组合物得到的树脂可用作具有高抗冲击性、高折射率和足够高的阿贝数的均衡光学材料。