catena-poly[[[1,8-bis(2-hydroxyethyl)-1,3,6,8,10,13-hexaazacyclotetradecane]copper(II)]-μcyano-[tricyanonitrosoiron(III)]-μ-cyano] | 716325-21-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: catena-poly[[[1,8-bis(2-hydroxyethyl)-1,3,6,8,10,13-hexaazacyclotetradecane]copper(II)]-μcyano-[tricyanonitrosoiron(III)]-μ-cyano]
• CAS: 716325-21-2
• 化学式: C₁₇H₃₀CuFeN₁₂O₃
• 分子量: 569.897
• InChiKey: QBIHOVHTTULMGK-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  disodium pentacyanonitrosylferrate(II) dihydrate 、 [copper(II)(3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexaazacyclotetradecane)](ClO₄)₂ 以 水 为溶剂， 生成 catena-poly[[[1,8-bis(2-hydroxyethyl)-1,3,6,8,10,13-hexaazacyclotetradecane]copper(II)]-μcyano-[tricyanonitrosoiron(III)]-μ-cyano]
  参考文献：
  名称：

  catena-Poly[[[1,8-bis(2-hydroxyethyl)-1,3,6,8,10,13-hexaazacyclotetradecane]copper(II)]-μ-cyano-[tricyanonitrosoiron(III)]-μ-cyano]

  摘要：

  The bimetallic title complex, [CuFe(CN)(5)(C12H30N6O2)(NO)] or [Cu(L) Fe(CN)(5)( NO)] [where L is 1,8-bis(2-hydroxyethyl)-1,3,6,8,10,13- hexaazacyclotetradecane], has a one-dimensional zigzag polymeric - Cu( L) - NC - Fe(NO)(CN)(3) - CN - Cu(L) - chain, in which the Cu-II and Fe-II centres are linked by two CN groups. In the complex, the Cu-II ion is coordinated by four N atoms from the L ligand [Cu - N( L) = 1.999 (2) - 2.016 (2) Angstrom] and two cyanide N atoms [Cu - N = 2.383 (2) and 2.902 (3) Angstrom], and has an elongated octahedral geometry. The Fe-II centre is in a distorted octahedral environment, with Fe - N(nitroso) = 1.656 (2) Angstrom and Fe - C(CN) = 1.938 (3) - 1.948 (3) Angstrom. The one-dimensional zigzag chains are linked to form a three-dimensional network via N - H..circleN and O-H ...N hydrogen bonds.

  DOI：

  10.1107/s0108270104004706