| 1397685-16-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡喃
• CAS: 1397685-16-3
• 化学式: C₂₄H₂₉N₂O₂*Cl
• 分子量: 412.959
• InChiKey: OZIWCKFKGKSFGD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  29.0
• 可旋转键数：
  2.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  28.62
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  在 氧化氘-18O 作用下， 生成
  参考文献：
  名称：

  Carbon–Carbon Bond Cleavage in Fluorescent Pyronin Analogues Induced by Yellow Light

  摘要：

  A novel class of pyronin analogues, which undergoes a photochemically induced cleavage of the C-C bond in the presence of water in both solution and on a silica gel surface upon direct irradiation with visible fight, is reported. The reaction course can be monitored by characteristic fluorescence of both the starting compound and the final product. This system could find useful applications in the field of photoremovable protecting groups or caged fluorophores.

  DOI：

  10.1021/ol302244f
• 作为产物：
  描述：

  甲醇 、 1-(9-(5-phenyl-1,3-dithian-2-yl)-6-(piperidin-1-yl)-3H-xanthen-3-ylidene)piperidin-1-ium chloride 生成
  参考文献：
  名称：

  Carbon–Carbon Bond Cleavage in Fluorescent Pyronin Analogues Induced by Yellow Light

  摘要：

  A novel class of pyronin analogues, which undergoes a photochemically induced cleavage of the C-C bond in the presence of water in both solution and on a silica gel surface upon direct irradiation with visible fight, is reported. The reaction course can be monitored by characteristic fluorescence of both the starting compound and the final product. This system could find useful applications in the field of photoremovable protecting groups or caged fluorophores.

  DOI：

  10.1021/ol302244f

文献信息

• Photochemistry of a 9‐Dithianyl‐Pyronin Derivative: A Cornucopia of Reaction Intermediates Lead to Common Photoproducts
  作者：Marek Martínek、Jiří Váňa、Peter Šebej、Rafael Navrátil、Tomáš Slanina、Lucie Ludvíková、Jana Roithová、Petr Klán

  DOI：10.1002/cplu.202000370

  日期：2020.10

  irradiation with visible light. However, the course of phototransformations of such photoactivatable systems can be quite complex and the identification of reaction intermediates or even products is often neglected. This paper exemplifies the photochemistry of a 9‐dithianyl‐pyronin derivative, which undergoes an oxidative transformation at the meso‐position to give a 3,6‐diamino‐9H‐xanthen‐9‐one derivative, formic

  留下附着于基团的内消旋许多常见染料，例如呫吨-甲基位置，BODIPY，或焦宁衍生物，可在用可见光照射解放。但是，这种可光活化系统的光转化过程可能非常复杂，并且常常忽略了对反应中间体甚至产物的鉴定。本文举例说明了9-噻烷基-焦宁衍生物的光化学，其经历在氧化转化的内消旋-位，得到3,6-二氨基-9- ħ黄嘌呤9一衍生物，甲酸和一氧化碳为主要光产物。通过稳态和时间分辨光谱，质谱和NMR光谱在各种条件下研究了这种多光子多步反应的过程，以了解溶剂和分子氧在各个步骤中的作用。我们的分析揭示了许多中间体的存在以及它们之间的相互关系，以提供对转化的完整描述，这可以为合理设计新的光活化性吡喃酮或or吨衍生物带来新的投入。