| 245038-90-8

• 分子结构分类: 有机化合物 - 有机金属化合物
• CAS: 245038-90-8
• 化学式: C₁₂H₃₇P₃RuSi
• 分子量: 403.503
• InChiKey: DTOCSDKSGDIGQY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.17
• 重原子数：
  17.0
• 可旋转键数：
  4.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  在 CO 作用下， 生成 mer-(CO)(PMe₃)3Ru(H)(SiMe₃)
  参考文献：
  名称：

  Formation and Interconversion of Ruthenium−Silene and 16-Electron Ruthenium Silyl Complexes

  摘要：

  DOI：

  10.1021/ja984363z
• 作为产物：
  描述：

  cis-(PMe3)4Ru(trimethylsilyl)H 在 triphenylborate 作用下， 以 环己烷 为溶剂， 生成
  参考文献：
  名称：

  Formation and Interconversion of Ruthenium−Silene and 16-Electron Ruthenium Silyl Complexes

  摘要：

  DOI：

  10.1021/ja984363z

文献信息

• Access to Unsaturated Ruthenium Complexes via Phosphine Complexation with Triphenylborane:  Synthesis and Structure of a Zwitterionic Arene Complex, (η⁶-Ph-BPh₂H)Ru(PMe₃)₂(SiMe₃)
  作者：Vladimir K. Dioumaev、Karl Plössl、Patrick J. Carroll、Donald H. Berry

  DOI：10.1021/om9908938

  日期：2000.8.1

  Triphenylborane, BPh3, serves as a phosphine "sponge", scavenging free PMe3 from alkane solutions of the 18e(-) complex (PMe3)(4)Ru(SiMe3)H to form sparingly soluble Ph3B-PMe3 and the 16e(-) (PMe3)(3)Ru(SiMe3)H. Under nitrogen atmosphere the 16e(-) (PMe3)Ru-3(SiMe3)H forms a dimeric N-2 adduct, [(PMe3)(3)Ru(SiMe3)H](2)N-2. Both the 16e(-) complex and its N-2 adduct exist in equilibrium with the 18e(-) silene complex, (PMe3)(3)Ru(CH2=SiMe2)H-2. However, long reaction times in the presence of excess borane leads to removal of another phosphine ligand as Ph3B-PMe3 and formation of a new zwitterionic complex, (eta(6)-PhBPh2H)Ru(PMe3)(2)(SiMe3) (5), in which a molecule of borane has abstracted a ruthenium hydride ligand and also coordinates as an eta(6)-arene. The merits and Limitations of BPh3 as a phosphine removal agent are discussed. Compound 5 has been characterized by single-crystal X-ray analysis and exhibits unusually long Ru-C-arene bonds.
• Tandemβ-CH Activation/SiH Elimination Reactions: Stabilization of CH Activation Products byβ-Agostic SiH Interactions
  作者：Vladimir K. Dioumaev、Patrick J. Carroll、Donald H. Berry

  DOI：10.1002/anie.200352078

  日期：2003.8.25