[Cu(II)(H(2,4,9,11-tetramethyl-dinaphtho[14]-2,4,6,9,11,13-hexaeneN4)(1-))](1+) | 1163688-63-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [Cu(II)(H(2,4,9,11-tetramethyl-dinaphtho[14]-2,4,6,9,11,13-hexaeneN4)(1-))](1+)
• CAS: 1163688-63-8
• 化学式: C₃₀H₂₇CuN₄
• 分子量: 507.117
• InChiKey: YUYPLBKOHQKMSU-ZFOGFPKBSA-N

反应信息

• 作为反应物：
  描述：

  [Cu(II)(H(2,4,9,11-tetramethyl-dinaphtho[14]-2,4,6,9,11,13-hexaeneN4)(1-))](1+) 在 叠氮阴离子 、 一氧化二氮 作用下， 以 水 、 乙腈 为溶剂， 生成 [Cu(III)(H(2,4,9,11-tetramethyl-dinaphtho[14]-2,4,6,9,11,13-hexaeneN4)(1-))](2+)
  参考文献：
  名称：

  Oligomerization of the Cu(II) and Ni(II) tetraazaannulene complexes: A pulse radiolysis study of the associated reaction mechanism

  摘要：

  The oligomerization of [Cu-II(H-x(tmdnTAA))](x+) (x = 0, 1, 2 and (tmdnTAA))(2) is 2,4,9,11-tetramethyl-dinaphto[14]-2,4,6,9,11,13-hexaeneN(4)) was initiated in homogeneous solution via the reaction of this Cu(II) complex with pulse radiolytically generated N-3(center dot) radicals. The reaction produces Cu(III) intermediates which are rapidly converted to Cu(II) ligand-radical species. In contrast to the mechanism proposed for the electrochemical oligomerization, where the local concentration of radicals is probably high, the reaction kinetics in homogeneous solution is propagated by a process where the Cu(II) ligand-radical precursors react with [Cu-II(H-x(tmdnTAA))](x+). (c) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.09.051