[N,N-bis(2-hydroxy-1-naphthaldehyde)-o-phenylenediamine] | 1021689-73-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [N,N-bis(2-hydroxy-1-naphthaldehyde)-o-phenylenediamine]
• 英文别名: nophen；N,N'-bis(2-hydroxynaphthalidene)phenylene-1,2-diamine；3-[[2-[(3-Hydroxynaphthalen-2-yl)methylideneamino]phenyl]iminomethyl]naphthalen-2-ol
• CAS: 1021689-73-5
• 化学式: C₂₈H₂₀N₂O₂
• 分子量: 416.479
• InChiKey: HMKSDDKVLSLIPF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  32
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  65.2
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  [N,N-bis(2-hydroxy-1-naphthaldehyde)-o-phenylenediamine] 、 zinc(II) chloride 以 甲醇 、 丙酮 为溶剂， 以88%的产率得到[Zn(N,N'-bis(2-hydroxynaphthalidene)phenylene-1,2-diamine(-2H))]
  参考文献：
  名称：

  Synthesis, characterization of N,N′-bis(2-hydroxynaphthalidene)phenylene-1,2-diamine with M(II)(M=Ni, Zn and Fe) Schiff-base complexes and their non-linear optical studies by z-scan technique

  摘要：

  Schiff-base complexes of N,N'-bis(2-hydroxynaphthalidene)phenylene-1,2-diamine ligand with metal M (M = Ni(II), Zn(II) and Fe(II)) have been synthesized and characterized by their UV, FT-IR, NMR, elemental analysis and magnetic susceptibility measurements. Non-linear optical measurements carried out using nanosecond laser pulses at 532 nm show that these complexes can be used for optical limiting applications. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.cplett.2010.05.040