| 57583-94-5

• 分子结构分类: 无机化合物
• CAS: 57583-94-5
• 化学式: AuF₆*FKr
• 分子量: 413.755
• InChiKey: ADMJIQUXXVDPNB-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  2.94
• 重原子数：
  9.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  氪(II)二氟化物 、 氢氟酸 、 金 以 氢氟酸 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and spectral properties of hexafluoroaurates

  摘要：

  It is established that krypton difluoride (KrF2) interacts with metallic gold in anhydrous hydrogen fluoride (HF) in the presence of alkaline and alkaline-earth metal fluorides with the formation of complex hexafluoroaurates with the general formula (MAuF6)-Au-I-F-V (M-I = Li, Na, K, Rb, Cs) and bis-hexafluoroaurates M-II((AuF6)-F-V)(2) (M-II = Mg, Ca, Sr, Ba). As a result of the subsequent interaction of bis-hexafluoroaurates with krypton difluoride, new coordination compounds with the composition M-II((AuF6)-F-V)(2) center dot nKrF(2) (M-II = Ca, Sr, Ba; n = 0-4) were synthesized. The Raman spectra were studied and a comparative analysis of the Raman spectra of the obtained compounds was performed. The possible variants of the structural transformation of the AuF (6) (-) anions in compounds and the position and character of the chemical bond of the "guest" (KrF2) in these compounds are discussed.

  DOI：

  10.1134/s0036024411110215