2,3-Bis--5,6-benzochinoxalin | 116665-69-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: 2,3-Bis--5,6-benzochinoxalin
• 英文别名: 2,3-di-pyridin-2-yl-benzo[f]quinoxaline；2,3-Bis(2-pyridyl)benzoquinoxaline；2,3-dipyridin-2-ylbenzo[f]quinoxaline
• CAS: 116665-69-1
• 化学式: C₂₂H₁₄N₄
• 分子量: 334.38
• InChiKey: LCPZKRMXSGJLTO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  26
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• SUPRAMOLECULAR COMPLEXES AS PHOTOCATYLYSTS FOR THE PRODUCTION OF HYDROGEN FROM WATER
  申请人：VIRGINIA TECH INTELLECTUAL PROPERTIES, INC.

  公开号：EP1836124A1

  公开（公告）日：2007-09-26
• Supramolecular complexes as photoactivated DNA cleavage agents
  申请人：——

  公开号：US20030180767A1

  公开（公告）日：2003-09-25

  The invention provides supramolecular metal complexes as DNA cleaving agents. In the complexes, charge is transferred from one light absorbing metal (e.g. Ru or Os) to an electron accepting metal (e.g. Rh) via a bridging &pgr;-acceptor ligand. A bioactive metal-to-metal charge transfer state capable of cleaving DNA is thus generated. The complexes function when irradiated with low energy visible light with or without molecular oxygen.
• SUPRAMOLECULAR COMPLEXES AS PHOTOCATALYSTS FOR THE PRODUCTION OF HYDROGEN FROM WATER
  申请人：Brewer J. Karen

  公开号：US20060286027A1

  公开（公告）日：2006-12-21

  Supramolecular complexes designed to produce hydrogen from water are provided. The supramolecular complexes absorb visible light and undergo charge transfer, leading to the collection of electrons at a reactive metal center, where the electrons reduce water to hydrogen. The complex remains intact during electron collection and hydrogen production.
• SUPRAMOLECULAR COMPLEXES AS PHOTOCATALYSTS FOR REDUCTION OF SUBSTRATES
  申请人：BREWER Karen J.

  公开号：US20080260633A1

  公开（公告）日：2008-10-23

  Supramolecular complexes, methods and systems for photocatalysis of the reduction of substrates are described. The supramolecular complexes of the invention have a light absorbing metal center, an electron collector ligand and a catalytically active metal. When the supramolecular complexes are exposed to radiant energy, the light absorbing metal center creates a charge that is transferred to the electron collector ligand to form a charge transfer state. The charge is then transferred through the catalytically active metal to a substrate, cause the reduction of the substrate, e.g. the reduction of water to molecular hydrogen.
• SUPRAMOLECULAR COMPLEXES AS PHOTOACTIVATED DNA CLEAVAGE AGENTS
  申请人：Brewer Karen

  公开号：US20100047910A1

  公开（公告）日：2010-02-25

  The invention provides supramolecular metal complexes as DNA cleaving agents. In the complexes, charge is transferred from one light absorbing metal (e.g. Ru or Os) to an electron accepting metal (e.g. Rh) via a bridging π-acceptor ligand. A bioactive metal-to-metal charge transfer state capable of cleaving DNA is thus generated. The complexes function when irradiated with low energy visible light with or without molecular oxygen.