N,N'-bis(2,3-dimethylphenyl)-1,1'-binaphthyl-2,2'-diamine | 1331748-58-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N,N'-bis(2,3-dimethylphenyl)-1,1'-binaphthyl-2,2'-diamine
• CAS: 1331748-58-3
• 化学式: C₃₆H₃₂N₂
• 分子量: 492.663
• InChiKey: KHKSSQKBYUVDHM-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  (2,3-dimethylphenyl)(2-naphthyl)amine 在 potassium carbonate 、 iron(III) chloride 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 5.08h， 以42%的产率得到N,N'-bis(2,3-dimethylphenyl)-1,1'-binaphthyl-2,2'-diamine
  参考文献：
  名称：

  Iron(III)-Promoted Oxidative Coupling of Naphthylamines: Synthetic and Mechanistic Investigations

  摘要：

  A facile route to the synthesis of 1,1'-binaphthyl-4,4'-diamines (naphthidines) and 1,1'-binaphthyl-2,2'-diamines (BINAMs) was developed by the oxidative homocoupling of 1- and 2-naphthylamines, respectively, using FeCl(3) as oxidant and K(2)CO(3) as base in 1,2-dichloroethane under ambient conditions. A preliminary mechanistic investigation was performed by the ESR spectroscopy and intermediate-trapping technique.

  DOI：

  10.1021/ol202058r