rhodium(3+);4-(2,3,4,5-tetramethylcyclopenta-1,3-dien-1-yl)-1,5-naphthyridine;dichloride | 1352928-94-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: rhodium(3+);4-(2,3,4,5-tetramethylcyclopenta-1,3-dien-1-yl)-1,5-naphthyridine;dichloride
• CAS: 1352928-94-9
• 化学式: C₁₇H₁₇Cl₂N₂Rh
• 分子量: 423.147
• InChiKey: YJFWYXVNEHTIHZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -1.75
• 重原子数：
  22
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  以 氘代氯仿 为溶剂， 以99%的产率得到rhodium(3+);4-(2,3,4,5-tetramethylcyclopenta-1,3-dien-1-yl)-1,5-naphthyridine;dichloride
  参考文献：
  名称：

  Synthesis and Complexation Behavior of Indenyl and Cyclopentadienyl Ligands Functionalized with a Naphthyridine Unit

  摘要：

  Lithium indenide (Li-Ind) or cyclopentadienide (Li-Cp) derivatives react as nucleophiles with 8-(methylsulfinyl)-1,5-naphthyridine (Naph), leading to donor-functionalized ligands Ind(Naph) or Cp-Naph, respectively. The new ligands comprise two N-donor atoms, which, for geometric reasons, cannot bind to the same metal atom. In complexes, where the metal atom is bound by the Cp or Ind moiety, the N5-donor atom is located in a distal position. The coordination behavior to Rh or Zr metal centers has been investigated. The Cp-based ligands show the expected chelating coordination mode with eta(5)-Cp and N coordination, whereas the indenyl units act as dihapto, trihapto, or pentahapto ligands. The dinuclear Rh(I) complex 12 shows a rare coordination geometry with two eta(3) ligands bridging a Rh-2(CO)(3) fragment.

  DOI：

  10.1021/om2009638