Zn(adipate)(1,10-phenanthroline)(H2O) | 442550-42-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: Zn(adipate)(1,10-phenanthroline)(H2O)
• 英文别名: Zn(adipate)(phen)(H2O)；[Zn(adipate)(1,10-phenanthroline)(H2O)]n
• CAS: 442550-42-7
• 化学式: C₆H₈O₄*C₁₂H₈N₂*H₂O*Zn
• 分子量: 407.741
• InChiKey: UQLNKZASORTIRE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  0.0
• 重原子数：
  26.0
• 可旋转键数：
  5.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  137.54
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  zinc(II) acetate dihydrate 、 1,10-菲罗啉 、 adipate dianion 在 NaOH 作用下， 以 水 为溶剂， 以71%的产率得到Zn(adipate)(1,10-phenanthroline)(H2O)
  参考文献：
  名称：

  Different aliphatic dicarboxylates affected assemble of new coordination polymers constructed from flexible–rigid mixed ligands

  摘要：

  In this article, seven coordination polymers: [Cd(C5H6O4)(C10H8N2)](n) (1), [Zn(C5H6O4)(C10H8N2)](n) (2), [Cd(C6H8O4)(C10H8N2)](n) (3), {[Mn(C10H8N2)(H2O)(4)] (C4H4O4) center dot 4H(2)O}(n) (4), [Mn-5(C4H4O4)(4)(O)](n) (5), [Cd(C4H4O4)(C10H8N2)(H2O)](n) (6) and [Zn(C6H6O4)(C12H8N2) (H2O)](n) (7) were synthesized and characterized by single-crystallographic X-ray diffraction. Compounds 1 and 2 are two-dimensional layers connected by glutarate anions and 4,4'-bpy. Unlike compounds 1 and 2, compound 3 is a two-fold interpenetration network. Compound 4 is a one-dimensional chain-like structure, which is further extended to two-dimensional supramolecular layer structure with hydrogen bond. During the synthesis of compound 4, to our surprise, we got compound 5; compound 5 is an interesting three-dimensional network composed of pentanuclear Mn(II) building units and succinate anions. Compound 6 is also a two-dimensional supramolecular layer structure composed of one-dimensional chain-like structure with hydrogen bonds and pi-pi interactions. Compound 7 is also a one-dimensional chain-like structure, which is further connected with the same kind of interaction to generate two-dimensional supramolecular layer structure. Furthermore, compounds 1 and 2 both exhibit fluorescent property at room temperature. (C) 2007 Published by Elsevier Inc.

  DOI：

  10.1016/j.jssc.2007.05.033

文献信息

• General Recyclable Redox-Metallothermic Reaction Route to Hierarchically Porous Carbon/Metal Composites
  作者：Kyung Joo Lee、Sinho Choi、Soojin Park、Hoi Ri Moon

  DOI：10.1021/acs.chemmater.6b01459

  日期：2016.6.28

  Herein, we develop a general synthetic route to obtain composites of porous carbon and electrochemically active metal particles such as Ge, In, Bi, and Sn. The thermolysis of a Zn-based metal–organic framework (MOF) produces hierarchically porous carbon (HPC) and metallic Zn at high temperatures, which can act as a reducing agent of metal oxides. In the reaction system of a Zn-based MOF with GeO2,

  本文中，我们开发了一种通用的合成路线，以获得多孔碳和电化学活性金属颗粒（如Ge，In，Bi和Sn）的复合材料。锌基金属-有机骨架（MOF）的热解在高温下会产生分层的多孔碳（HPC）和金属Zn，它们可以充当金属氧化物的还原剂。Zn基MOF与GeO 2的反应体系中，原位生长的Zn还原GeO 2。，生成Ge和ZnO。有趣的是，ZnO在转化过程中通过碳热还原自动还原为Zn，这使还原剂返回到反应中。因此，锌热还原反应和碳热还原反应的重复发生促进了可循环的氧化还原-金属热反应。GeO 2完全还原后，锌金属自发蒸发，生成Ge / HPC复合材料。这种简便的方法可以成功地扩展到其他金属氧化物，包括In 2 O 3，Bi 2 O 3和SnO。合成后的Ge / HPC已作为可充电电池阳极材料进行了测试，其可逆容量高达600 mA hg –1 300次循环后，速率为0.5 C，电极体积膨胀率低（小于30％）。
• Adipato-Bridged Mixed Ligand catena Complexes: ${_{\infty}^1}${[M(phen)(H2O)]L2/2} with M = NiII, CuII, ZnII; H2L = Adipic Acid
  作者：Yue-Qing Zheng、Wen-Han Liu、Jian-Li Lin、Lin-Yun Gu

  DOI：10.1002/1521-3749(200205)628:4<829::aid-zaac829>3.0.co;2-a

  日期：2002.5

  Three adipato bridged mixed ligand catena complexes 1proportional to[M(phen)(H2O)]-(C6H8O4)(2/2)} with M = Ni-II (1), Cu-II (2), Zn-II (3) were synthesized. Structure determination based on X-ray diffraction shows that they crystallize isostructurally in the monoclinic space group C2/c (no. 15) with cell dimensions of: 1 a = 22,451(4) Angstrom, b = 9.041(1) Angstrom. c = 17.440(2) Angstrom, beta = 103.41(1)degrees, U = 3443.4(9) Angstrom(3). Z = 8; 2 a = 22.479(2) Angstrom, b = 9.067(1) Angstrom, c = 17.494(3) Angstrom, beta = 103.67(1)degrees, U = 3464.6(8) Angstrom(3), Z = 8; 3 a = 22.635(3) Angstrom. b = 9.052(1) Angstrom, c = 17.571(3) Angstrom, beta = 103.24(1), U = 3504.5(9) Angstrom(3), Z = 8. The crystal structure consists of ID1proportional to[M(phen)(H2O)](C6H8O4)(2/2) zigzag chains. in which the metal atoms are all octahedrally coordinated by two N atoms of one phen ligands and four O atoms of one H2O molecule and two adipato ligands. The zigzag chains are held together by interchain pi-pi stacking interactions and interchain hydrogen bonds.