5,10,15,20-tetrakis(4-dimethylaminophenyl)porphin iron | 119088-91-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 5,10,15,20-tetrakis(4-dimethylaminophenyl)porphin iron
• CAS: 119088-91-4
• 化学式: C₅₂H₄₈FeN₈
• 分子量: 840.854
• InChiKey: SFJXSSWIWLESGS-YOPYOQPVSA-N

反应信息

• 作为产物：
  描述：

  iron(II) chloride 、 meso-tetrakis(4'-dimethylaminophenyl)porphyrin 以 N,N-二甲基甲酰胺 为溶剂， 以12%的产率得到5,10,15,20-tetrakis(4-dimethylaminophenyl)porphin iron
  参考文献：
  名称：

  Synthesis of 5,10,15,20-Tetrakisphenylporphins on a Carbon Support for the Cathodic Reduction of Oxygen in Fuel Cells

  摘要：

  AbstractSeveral substituted Fe‐ and Co‐containing tetraphenylporphins 1 were loaded on carbon either by adsorption from acetone or by in situ synthesis on the carbon support. The porphin/carbon combinations were pyrolyzed at 800°C. The electrocatalytic activities in the reduction of dioxygen were investigated in alkaline (KOH) and acid (H2SO4) solutions using porous Teflon‐bonded carbon electrodes impregnated with the catalysts. At 700 mV high current densities of 75 mA/cm2 in acid solution and up to 90 mA/cm2 in alkaline solution were obtained.

  DOI：

  10.1002/bbpc.198800335