2-[(2E)-4,4-dimethylpent-2-en-1-yl]-3,5-dimethoxyphenol | 1432498-11-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2-[(2E)-4,4-dimethylpent-2-en-1-yl]-3,5-dimethoxyphenol
• CAS: 1432498-11-7
• 化学式: C₁₅H₂₂O₃
• 分子量: 250.338
• InChiKey: OEMGTYRMWDKVSZ-SOFGYWHQSA-N

反应信息

• 作为产物：
  描述：

  在 sodium tetrahydroborate 、 cerium(III) chloride heptahydrate 作用下， 以 乙醇 为溶剂， 反应 0.67h， 生成 2-[(2E)-4,4-dimethylpent-2-en-1-yl]-3,5-dimethoxyphenol
  参考文献：
  名称：

  Deoxygenation of α,β-unsaturated acylphenols through ethyl o-acylphenylcarbonates with Luche reduction

  摘要：

  An efficient protocol for deoxygenation of alpha,beta-unsaturated acylphenols through ethyl o-acylphenylcarbonates with Luche reduction is described. The reaction shows very good selectivity and tolerates a wide range of functionalities on alpha,beta-unsaturated acylphenols, giving corresponding 2-allylphenols in good to excellent yields. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.02.109