Os3(μ-H)(μ-2-OC10H7)(CO)8(SbPh3)2*CH2Cl2 | 680219-79-8

• 英文名称: Os3(μ-H)(μ-2-OC10H7)(CO)8(SbPh3)2*CH2Cl2
• CAS: 680219-79-8
• 化学式: CH₂Cl₂*C₅₄H₃₈O₉Os₃Sb₂
• 分子量: 1729.92
• InChiKey: MMADHZJEBWJOHV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二氯甲烷 、 Os3(μ-H)(μ2-1-OC10H7)(CO)10 、 三苯基锑 在 trimethylamine-N-oxide dihydrate 作用下， 以 二氯甲烷 为溶剂， 以20%的产率得到Os3(μ-H)(μ-2-OC10H7)(CO)9(SbPh3)
  参考文献：
  名称：

  Organo-Group 15 derivatives of triosmium clusters containing naphthyl ligands

  摘要：

  Reactions of the clusters Os-3(mu-H)(2)(mu(3)-1-OC10H6)(CO)(9), 1, and Os-3(mu-H)(mu-2-OC10H7)(CO)(10), 2, with the group 15 ligands EPh3 (E = P, As, Sb) generally afforded the mono- and, or disubstituted derivatives. These derivatives tend to decompose during chromatographic separations on silica gel; thus one of the decomposition products from the reaction of 1 with PPh3 has been identified as Os(H)(2)(CO)(2)(PPh3)(2), 3. The molecular structures of 3, as well as the derivatives Os-3(mu-H)(2)(mu(3)-1-OC10H6)(CO)(8)(AsPh3), 4, Os-3(mu-H)(2)(mu(3)-1-OC10H6)(CO)(7)(SbPh3)(2), 5c, Os-3(mu-H)(mu-2-OC10H7)(CO)(8)(AsPh3)(2), 7b, and Os-3(mu-H)(mu-2-OC10H7)(CO)(8)(SbPh3)(2), 7c, have been determined by single crystal X-ray diffraction studies. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.09.001